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New Theory and Applications of Quantitative Analysis

机译：定量分析的新理论与应用

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Since all thermal reactions almost conduct under the unsteady conditions and those parameters including concentration and flow rate of evolved gas also change with the temperature or pressure, it is hard to clearly describe the reaction feature by only one parameter such as concentration in the Arrhenius equation. In fact, the concentration only indicates the relationship between the individual value and the total value of evolved gas. Thus, even if the concentration of some components in one complicated reaction increases, the real reaction would not increase since the other components maybe increase more intensively. On the contrary, the flow rate can give persuasive information to understand the characteristic of these reactions. A novel method of Equivalent Characteristic Spectrum Analysis (ECSA) has given the flow rate of all components, including mass flow rate or molar flow rate, by mass spectrum of TG-MS. This technology has been applied to analyze the feature of reaction process. As some applications in the materials field, ECSA has exactly detected the flow rate of hydrogen in the materials of storage hydrogen to evaluate its performance and construction. In the fossil energy, ECSA has found some principles how to control the pollutants and metal elements releasing problems during coal conversion. At present, ECSA has developed deeply to explain precisely the organic thermal reaction of biomass, oil, polymer, paraffin and so on since it has been applied to new instrument with double modes of EI and PI ionization and Skimmer interface for actual in-suit detect.
机译：由于所有热反应几乎都在不稳定条件下进行，并且放出气体的浓度和流量等参数也会随温度或压力而变化，因此很难仅通过一个参数（例如阿伦尼乌斯方程中的浓度）清楚地描述反应特征。实际上，浓度仅表示个体值与放出气体的总值之间的关系。因此，即使一个复杂反应中某些成分的浓度增加，实际反应也不会增加，因为其他成分可能会更强烈地增加。相反，流速可以提供有说服力的信息，以了解这些反应的特征。等效特征谱分析（ECSA）的一种新方法通过TG-MS质谱图给出了所有组分的流速，包括质量流速或摩尔流速。该技术已被用于分析反应过程的特征。作为材料领域的某些应用，ECSA准确地检测了储氢材料中的氢气流速，以评估其性能和结构。在化石能源中，ECSA发现了一些原理，以控制煤转化过程中污染物和金属元素的释放问题。目前，由于ECSA已被应用于具有EI和PI电离双模式以及Skimmer接口进行实际室内检测的新仪器中，因此已深入发展以精确地解释生物质，油，聚合物，石蜡等的有机热反应。 。

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