New organometallic materials for nonlinear optics: metal -arylacetylides

机译：用于非线性光学的新型有机金属材料：金属-芳基乙炔化物

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Abstract: Hyper-Rayleigh scattering is used to investigate the nonlinear optical properties of novel organometallic compounds. For a series of ruthenium and gold $sigma@- arylacetylides, including some bimetallic complexes, the influence of the organometallic donor group, chain length and type of acceptor on the quadratic hyperpolarizability is studied. The hyperpolarizabilities found are among the highest (10$+$MIN@27 esu) known for organometallic compounds. Moreover, electric-field induced second-harmonic generation confirms these values and indicates that only one major tensor component is present.!29

机译：摘要：超瑞利散射用于研究新型有机金属化合物的非线性光学性质。对于包括一些双金属配合物的一系列钌和金$ sigma @-芳基乙炔化物，研究了有机金属供体基团，链长和受体类型对二次超极化性的影响。发现的超极化性是已知的有机金属化合物中最高的（10 $ + MINMIN @ 27 esu）。此外，电场感应的二次谐波产生证实了这些值，并表明仅存在一个主要的张量分量！29

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《Nonlinear Optical Properties of Organic Materials IX》|1996年|p.98-108|共11页
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Stephan Houbrechts; Univ. of Leuven; Leuven; Belgium; Koen J. Clays; Univ. of Leuven; Leuven; Belgium; Andre P. Persoons; Univ. of Leuven; Holsbeek; Belgium; Victorio Cadierno; Univ. de Oviedo; Oviedo; Spain; M.P. Gamasa; Univ. de Oveido; Oveido; Spain; Jose Gimeno; Univ. de Oviedo; Oviedo; Spain; Ian R. Whittall; Australian National Univ.; Canberra ACT; Australia; Mark G. Humphrey; Australian National Univ.; Canberra ACT; Australia.;
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1. ORGANOMETALLIC COMPLEXES FOR NONLINEAR OPTICS .2. SYNTHESES, ELECTROCHEMICAL STUDIES, STRUCTURAL CHARACTERIZATION, AND COMPUTATIONALLY-DERIVED MOLECULAR QUADRATIC HYPERPOLARIZABILITIES OF RUTHENIUM SIGMA-ARYLACETYLIDES - X-RAY CRYSTAL STRUCTURES OF R [J] . Whittall IR., Hockless DCR., Humphrey MG. Organometallics . 1995,第8期

机译：非线性光学的有机复合物.2。 R-X射线晶体的合成，电化学研究，结构表征和计算衍生的分子二次超极化-R的X射线晶体结构
2. Organometallic Complexes for Nonlinear Optics. 22. Quadratic and Cubic Hyperpolarizabilities of trans-Bis(bidentate phosphine)ruthenium #sigma#-Arylvinylindene and #sigma#-Arylalkynyl Complexes [J] . Stephanie K. Hurst, Marie P. Cifuentes, Joseph P. L. Morrall, Organometallics . 2001,第22期

机译：非线性光学的有机金属配合物。 22.双-双（双膦）钌＃sigma＃-芳基乙烯基茚和＃sigma＃-芳基炔基配合物的二次和立方超极化率
3. Organometallic complexes for nonlinear optics. 15. Molecular quadratic hyperpolarizabilities of trans-bis{bis(diphenylphosphino)methane}ruthenium sigma-aryl- and sigma-pyridyl-acetylides: X-ray crystal structure of trans-[Ru(2-C CC5H3N-5-NO2)Cl(dppm [J] . Naulty RH., Whittall IR., Cifuentes MP., Journal of Organometallic Chemistry . 1998,第1a2期

机译：非线性光学的有机金属配合物。 15.反式双{双（二（二苯基膦基）甲烷}钌]σ-芳基-和σ-吡啶基-乙炔化物的分子二次超极化性：反式-[Ru（2-C CC5H3N-5-NO2）Cl（百万分之几
4. New organometallic materials for nonlinear optics: metal -arylacetylides [C] . Stephan Houbrechts, Koen J. Clays, Andre P. Persoons, Conference on Nonlinear Optical Properties of Organic Materials . 1996

机译：非线性光学器材新的有机金属材料：金属 - 丙炔
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机译：铂和铱有机金属材料的光物理：从分子线到非线性光学
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机译：用于非线性光学器件的有机金属复合物。 42.连接金属官能化寡核苷酸（对亚苯基乙烯）的合成，线性和非线性光学性能

New organometallic materials for nonlinear optics: metal -arylacetylides

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