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Formation of gel inclusions in potassium dihydrogen phosphate crystals growing in tetramethoxysilane gel by temperature decrease method

机译:降温法在四甲氧基硅烷凝胶中生长的磷酸二氢钾晶体中形成凝胶包裹体

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Abstract: The paper presents the investigations of gel inclusion formation in potassium dihydrogen phosphate (KDP) crystals grown in tetramethoxysilane (TMS) gel in relation to growth conditions i.e. KDP concentration in gel, gel density and cooling rate. The experiments show that increasing of KDP concentration in gels with the same density promotes formation of gel inclusions in KDP crystals. Increasing of gel density causes greater gel contamination in crystals even if KDP concentration in gels is maintained at the same level. Formation of gel inclusions in crystals may be suppressed if the temperature of gels is decreased very slowly. It was concluded that high supersaturation of solution in gel during nucleation and growth is responsible for the formation of gel inclusions. !21
机译:摘要:本文介绍了在四甲氧基硅烷(TMS)凝胶中生长的磷酸二氢钾(KDP)晶体中凝胶包裹体形成与生长条件有关的研究,即KDP在凝胶中的浓度,凝胶密度和冷却速率。实验表明,以相同密度增加凝胶中KDP的浓度会促进KDP晶体中凝胶夹杂物的形成。即使凝胶中的KDP浓度保持在同一水平,凝胶密度的增加也会导致晶体中更大的凝胶污染。如果凝胶温度非常缓慢地降低,则可以抑制晶体中凝胶夹杂物的形成。得出的结论是,成核和生长过程中凝胶中溶液的过饱和度高,是形成凝胶夹杂物的原因。 !21

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