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THERMAL MANAGEMENT IN THE MEASUREMENT OF METAL HYDRIDE KINETICS

机译:金属氢化物动力学测量中的热管理

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Many metal hydride nanopowders are currently being investigated as a potential hydrogen storage media. The kinetic properties of hydrogen absorption in TiCrMn, a metal hydride of interest, are largely unknown. This study will use coupled thermal and kinetic modeling to analyze a combination of novel and well-established techniques which can be used to experimentally determine these parameters. Since these measurements must be taken at isothermal conditions and the metal hydride absorption reaction is highly exothermal, specific thermal considerations must be made in these models.Typical instruments available for kinetics measurements suspend the samples in a small chamber, effectively thermally isolating them from the cooling or heating system designed to control sample temperature. The design modeled herein will eliminate that convective resistance layer, thereby increasing the amount of heat that can be rapidly diffused out of the sample. Additionally, an electronically controlled active temperature control system will be modeled as a method of maintaining "quasi-isothermal" conditions in the metal hydride during measurements.
机译:目前正在研究许多金属氢化物纳米粉作为潜在的氢存储介质。 TiCrMn(一种感兴趣的金属氢化物)中氢吸收的动力学特性在很大程度上是未知的。这项研究将使用热力学和动力学耦合模型来分析新颖和成熟的技术的组合,这些技术可用于通过实验确定这些参数。由于这些测量必须在等温条件下进行,并且金属氢化物吸收反应是放热性很高的,因此在这些模型中必须考虑特定的热因素。 可用于动力学测量的典型仪器将样品悬浮在一个小室内,有效地将它们与设计用于控制样品温度的冷却或加热系统热隔离。本文建模的设计将消除该对流阻力层,从而增加可快速扩散出样品的热量。另外,将电子控制的主动温度控制系统建模为在测量期间在金属氢化物中保持“准等温”状态的方法。

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