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EFFECT OF SIZE ON PROPERTIES OF NANO-STRUCTURED POLYMERS -TRANSITION FROM MACROSCALING TO NANOSCALING

机译:尺寸对纳米结构聚合物性能的影响-从宏观尺度到纳米尺度的转变

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摘要

The growth in investment on the effect of size in nanoscience and nanotechnology has been astounding. Of the $12.4B spent in 2006 worldwide Nanotechnology research funding [1], at least 50 % was spent on the effect of size for the development of nanomaterials and devices. The focus of nanoscience is to understand the influence of size on the material properties, while nanotechnology focuses on using size effects to create structures, devices and systems with novel properties and functions.Based on literature data, we have demonstrated that a modified Hall-Petch relation is useful to relate the observed "effective" nanosize to physical properties. Several viscoelastic models have been developed to explain the role surface molecular dynamics plays in thermal mechanical behavior. The polymers examined including polystyrene, polymethyl methacrylate, and Metafuse?.
机译:对纳米科学和纳米技术规模效果的投资增长已经令人惊讶。在2006年的12.4B美元中,全球纳米技术研究资金[1],至少50%用于纳米材料和装置的发展效果。纳米科学的焦点是了解大小对材料特性的影响,而纳米技术侧重于使用大小效应来创建具有新颖性和功能的结构,设备和系统。 基于文献数据,我们已经证明了改进的霍尔 - Petch关系是有用的,使观察到的“有效”纳米化与物理性质相关。已经开发出几种粘弹性模型来解释角色表面分子动力学在热力学行为中发挥作用。检查包括聚苯乙烯,聚甲基丙烯酸甲酯和梅布布的聚合物。

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