首页> 外文会议>European corrosion congress;EUROCORR 2010 >The protective conversion coatings on A7075 aluminum alloy, obtained in alkaline converting solutions.
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The protective conversion coatings on A7075 aluminum alloy, obtained in alkaline converting solutions.

机译:在碱性转化溶液中获得的A7075铝合金上的保护性转化膜。

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High-strength V95 aluminum alloy (Russian analogue of A7075 alloy) belongs to Al-Mg-Cu-Zn system. These alloys possess low corrosion resistance in atmospheric and water environments. The application of molybdate solutions for chemical oxidizing of aluminum alloys is one of perspective trends of chromateless converting formulations development. It has been shown earlier, that it is possible to obtain the chromateless conversion coatings on aluminum-magnesium alloys and aluminum-copper alloys of Al-Mg-Cu system in alkaline molybdate formulations modified by various oxidizers and corrosion inhibitors. The coatings with high protective properties were formed in the investigated converting formulations. In this connection, a study of chemical oxidizing in such converting formulations of V95 aluminum alloy with various heat treatments seemed interesting. The kinetics of conversion coatings formation on V95 alloys with various heat pretreatments in alkaline molybdate-borate converting formulations and their protective properties in chloride solutions were investigated by corrosion and electrochemical methods. The regularities of influence of the developed chromateless converting formulation IFHANAL-3 components on the protective properties and structure of conversion coatings on V95 alloy are revealed with the use of x-ray spectral microanalysis methods. It is shown, that low corrosion resistance to local anode activation in chloride solutions of coatings on alloy V95 is connected with their enrichment with zinc and copper oxides. The filling of the obtained conversion coatings in a solution of IFHAN-25 inhibitor increases their protective properties to chromate coatings level due to the adsorption inhibitor film formation on a coating surface. The tests of such coatings in the salt fog chamber have shown that their corrosion resistance exceeds 168 hours.
机译:高强度V95铝合金(A7075合金的俄罗斯类似物)属于Al-Mg-Cu-Zn系。这些合金在大气和水环境中具有较低的耐腐蚀性。钼酸盐溶液在铝合金的化学氧化中的应用是无铬转化配方发展的趋势之一。先前已经表明,可以在由各种氧化剂和腐蚀抑制剂改性的碱性钼酸盐配方中,在Al-Mg-Cu体系的铝镁合金和铝铜合金上获得无铬酸盐转化膜。在研究的转化配方中形成了具有高保护性能的涂料。在这方面,对用各种热处理的V95铝合金的这种转化配方中的化学氧化的研究似乎是有趣的。通过腐蚀和电化学方法研究了在碱金属钼酸盐-硼酸盐转化配方中经过各种热处理的V95合金上转化膜形成的动力学及其在氯化物溶液中的保护性能。利用X射线光谱显微分析方法揭示了开发的无铬转化配方IFHANAL-3组分对V95合金转化膜的防护性能和结构的影响规律。结果表明,在合金V95的涂层的氯化物溶液中,对局部阳极活化的低耐腐蚀性与其在锌和铜氧化物中的富集有关。通过在IFHAN-25抑制剂的溶液中填充获得的转化涂层,由于在涂层表面上形成了吸附抑制剂膜,从而提高了其对铬酸盐涂层水平的保护性能。在盐雾室中对此类涂层的测试表明,其耐蚀性超过168小时。

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