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Research of new process preparing potassium sulfate from phosphogypsum

机译:磷石膏制硫酸钾新工艺研究

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To improve the process of potassium sulphate prepared from phosphogypsum (under study, no product, only method) in ammonia solution, the influence of solvent such as Methanol, Methanol-ammonia on the yield of potassium oxide was studied. The result revealed that the system of ethanol and ammonia was optimal. Meanwhile, the process of potassium sulphate prepared from phosphogypsum in the system of ethanol and ammonia was also investigated. The optimum conditions was obtained:6% ethanol, concentration of 25% ammonia solution, reaction temperature 25°C, reaction time 1.5h, liquid to solid ratio 5.0∶1, charge ratio 1.15∶1. Under this condition, obtained product of Potassium hydroxide mass fraction 41%, potassium hydroxide yields was about 75%.
机译:为了改善磷石膏制硫酸钾的工艺(研究中,没有产品,只有方法),研究了甲醇,甲醇-氨等溶剂对氧化钾收率的影响。结果表明,乙醇和氨水体系是最佳的。同时,还研究了由磷石膏制乙醇和氨水制硫酸钾的过程。获得了最佳条件:乙醇为6%,氨溶液浓度为25%,反应温度为25°C,反应时间为1.5h,液固比为5.0:1,装料比为1.15:1。在此条件下,制得的氢氧化钾质量分数为41%,氢氧化钾收率约为75%。

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