Preparation of Small Crystalline ZSM-5 and Its Application in Conversion of Methanol to Aromatic

机译：ZSM-5小晶体的制备及其在甲醇制芳烃中的应用

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Small crystalline ZSM-5 was synthesized by a hydrothermal synthesis procedure and was characterized by XRD, SEM and N2-absorption. The results show that small crystalline ZSM-5 particles grow into larger agglomerates with a diameter of 100-400 nm, resulting in mesopore and higher surface area. During conversion of methanol to aromatics, small crystalline ZSM-5 catalyst performances better than micron-size ZSM-5 catalyst in aromatic selectivity and lifetime. The aromatic selectivity could reach to 21.7%, and the small crystalline ZSM-5 catalyst shows no deactivation during first 24h.

机译：通过水热合成方法合成了小晶体ZSM-5，并通过XRD，SEM和N2吸收进行了表征。结果表明，小的晶体ZSM-5颗粒会长成直径为100-400 nm的较大的团聚体，从而导致中孔和更大的表面积。在甲醇转化为芳烃的过程中，小晶体ZSM-5催化剂在芳烃选择性和寿命方面的性能优于微米级ZSM-5催化剂。芳烃的选择性可以达到21.7％，并且小结晶ZSM-5催化剂在最初的24小时内没有失活。

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《International conference on advanced materials and engineering materials》|2012年|245-248|共4页
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Jianjun Song; Zuoxing Di; Cheng Yang; Jinhu Wu;
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中图分类工程材料学;
关键词
small crystalline; ZSM-5; methanol; aromatic; MTA;

机译：小晶体; ZSM-5;甲醇;芳烃; MTA;

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1. Facile One-Pot Synthesis of ZSM-5 Aggregates with Inter-and Intra-Crystalline Mesopores for Methanol to Gasoline Conversion [J] . Yaquan Wang, Chunyang Fan, Hongyao Li, 天津大学学报（英文版） . 2019,第001期

机译：ZSM-5聚集体与晶体间和晶体内介孔的甲醇的轻松一锅合成转化为汽油。
2. Co-conversion of methanol and n-hexane into aromatics using intergrown ZSM-5/ZSM-11 as a catalyst [J] . Shumei Wei, Yarong Xu, Zhaoyang Jin, Frontiers of chemical science and engineering . 2020,第5期

机译：使用白天ZSM-5 / ZSM-11作为催化剂将甲醇和正己烷与芳烃的共转化为芳烃
3. Influence of Hollow ZSM-5 Zeolites Prepared by Treatment with Different Alkalis on the Catalytic Conversion of Methanol to Aromatics [J] . Wen-yuan Jin, Ji-rong Qiao, Jun-ping Yu, Energy & fuels . 2020,第11期

机译：用不同碱对甲醇催化转化为芳烃的甲醇催化转化制备的中空ZSM-5沸石的影响
4. Preparation of Small Crystalline ZSM-5 and Its Application in Conversion of Methanol to Aromatic [C] . Jianjun Song, Zuoxing Di, Cheng Yang, ICAMEM 2011 . 2012

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5. Selective conversion of methanol into hydrocarbons on chryso-zeolite or zeolite ZSM-5 catalysts [D] . Levesque, Pierre 1987

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6. Preparation of sub-microspherical Fe3O4@PDA-Pd NPs catalyst and application in catalytic hydroreduction reaction of halogenated aromatic nitro compounds to prepare halogenated aromatic amines [O] . Haichang Guo, Renhua Zheng, Huajiang Jiang, 2019

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7. Forming pure shaped ZSM-5 zeolite bodies by a steam-assisted method and their application in methanol to aromatic reactions [O] . Junwen Wang, Xiaofeng Gao, Guoliang Chen, 2019

机译：通过蒸汽辅助方法形成纯成形的ZSM-5沸石体及其在甲醇中的芳族反应中的应用
8. Preparation and Characterization of Ligand Types Intermediate in the Metal Catalyzed Conversion of Coal to Methane, Methanol, and Higher Alkanes and Alcohols. Final Progress Report, September 1, 1978-June 30, 1982 [R] . Truhan, J. J., Aceves, S. C., McCright, R. D. 1982

机译：金属催化煤转化为甲烷，甲醇和高级烷烃和醇的中间体配体类型的制备和表征。最终进展报告，1978年9月1日至1982年6月30日

Preparation of Small Crystalline ZSM-5 and Its Application in Conversion of Methanol to Aromatic

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