Deuterium Isotope Effects, △pK = pK_(D2O) - pK_(H2O) on the Second Dissociation of Carbonic Acid by Raman Spectroscopy

机译：氘同位素对拉曼光谱法对碳酸第二次解离的影响△pK = pK_（D2O）-pK_（H2O）

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Polarized Raman spectroscopy has been used to measure the deuterium isotope effect, △pK = pK_(D2O) - pK_(H2O), for the second ionization constant of carbonic acid in the temperature range of 25 °C to 125 °C, CO_3~(2-) + D_2O (⇔) DCO_3~- + OD~- .Results for the light water pK dependence on temperature were compared to literature, confirming the reliability of the method.

机译：在25°C至125°C的温度范围内，碳酸的第二个电离常数已使用极化拉曼光谱法测量氘同位素效应△pK = pK_（D2O）-pK_（H2O） 2-）+ D_2O（⇔）DCO_3〜-+ OD〜-。将淡水pK随温度变化的结果与文献进行了比较，证实了该方法的可靠性。

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《Annual conference of the Canadian Nuclear Society;CNS/CNA student conference》|2013年|1186-1190|共5页
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J. Noel; L.M.S.G.A. Applegarth; P.R. Tremaine;
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1. Second Dissociation Constant of Carbonic Acid in H2O and D2O from 150 to 325 degrees C at p=21 MPa Using Raman Spectroscopy and a Sapphire-Windowed Flow Cell [J] . Conrad Jacy, Sasidharanpillai Swaroop, Tremaine Peter R. The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2020,第13期

机译：使用拉曼光谱和蓝宝石窗口流动细胞，在P = 21MPa的H 2 O和D2O中碳酸的第二个解离常数在150至325摄氏度下
2. Deuterium Isotope Effects on the Ionization Constant of Acetic Acid in H2O and D2O by AC Conductance from 368 to 548 K at 20 MPa (vol 115, pg 3038, 2011) [J] . Erickson K. M., Arcis H., Raffa D., The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2019,第44期

机译：氘同位素在20MPa（Vol 115，PG 3038,2011）的368至548K中，AC电导通过368至548k的乙酸在H 2 O和D2O中的电离常数作用
3. Deuterium Isotope Effects on the Ionization Constant of Acetic Acid in H2O and D2O by AC Conductance from 368 to 548 K at 20 MPa [J] . K. M. Erickson, H. Aicis, D. Raffa The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2011,第12期

机译：在20 MPa下368〜548 K交流电氘同位素对H2O和D2O中乙酸电离常数的影响。
4. Deuterium Isotope Effects, ΔpK = pK_(D2O) - pK_(H2O), on the Second Dissociation of Carbonic Acid by Raman Spectroscopy [C] . J. Noel, L.M.S.G.A. Applegarth, P.R. Tremaine Conference of the Canadian Nuclear Society . 2013

机译：氘同位素效应，ΔPK= PK_（D2O） - PK_（H2O）通过拉曼光谱法在碳酸的第二个解离
5. Enthalpy and Entropy in Chemical Reactivity: I. Temperature Dependence of Secondary Deuterium Isotope Effects on the Acidity of Carboxylic Acids and Phenols, and a Rejection of any Inductive Contribution II. Kinetic and Mechanistic Studies of Reactions of Malonic Anhydrides III. Developing an ITC Method to Measure Heats of Proton Transfer [D] . Flach, Agnes 2012

机译：化学反应的焓和熵：I.次级氘同位素的温度依赖性对羧酸和苯酚酸度的影响，以及任何感应贡献的抑制II。丙二酸酐反应的动力学和机理研究。开发用于测量质子传递热的ITC方法
6. Characterization of DNA structures by Raman spectroscopy: high-salt and low-salt forms of double helical poly(dG-dC) in H2O and D2O solutions and application to B Z and A-DNA. [O] . J M Benevides, G J Thomas Jr 1983

机译：DNA结构的拉曼光谱表征：H2O和D2O溶液中双螺旋聚（dG-dC）的高盐和低盐形式并应用于BZ和A-DNA。
7. Correction to “Deuterium Isotope Effects on the Ionization Constant of Acetic Acid in H2O and D2O by AC Conductance from 368 to 548 K at 20 MPa” [O] . K. M. Erickson, H. Arcis, D. Raffa, 2019

机译：在20MPa的368至548k中，通过368至548k校正“在H2O和D2O中乙酸中乙酸电离常数的氘化同位素效应”

Deuterium Isotope Effects, △pK = pK_(D2O) - pK_(H2O) on the Second Dissociation of Carbonic Acid by Raman Spectroscopy

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