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Composites of zinc phosphate glass/metal: New materials for thermoelectricity and solar cell devices

机译:磷酸锌玻璃/金属复合材料:用于热电和太阳能电池设备的新材料

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This work reports a study on thermoelectricity in new composites zinc-phosphate glasses/cobalt. The obtained Seebeck coefficient (S) changes a sign from a high positive to negative values below and above the percolation threshold, respectively, showing p-n type conducting phase transition. Thus, the Seebeck coefficient measurements above the percolation threshold as function of temperature showed respectively an original conducting to insulating phase transition at T=420K, linked with a high negative value of S≤-8000μV/K, giving rise to the highest power factor PF=σS≈8×103W.m1.K2. The thermal measurements confirm this transition and indicate a dilation of matrix around this temperature. Such materials with high Seebeck coefficient could be used as new materials for thermoelectricity applications. In addition, the p-n transition in these materials my fined useful application in p-n junction devices.
机译:这项工作报告了新型复合磷酸锌玻璃/钴中热电的研究。所获得的塞贝克系数(S)将符号从高正值分别更改为低于和高于渗透阈值的负值,表示p-n型传导相变。因此,超过渗滤阈值的塞贝克系数测量值是温度的函数,分别显示了在T = 420K时原始的传导至绝缘的相变,并伴随着S≤-8000μV/ K的高负值,从而产生了最高的功率因数PF =σS≈8×103W.m1.K2。热测量结果证实了这种转变,并表明该温度附近基质的膨胀。具有高塞贝克系数的这种材料可以用作热电应用的新材料。此外,这些材料中的p-n跃迁在p-n结器件中得到了很好的应用。

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