Synthesis and Characterization of Novel Energetic Oxirane Monomers Containing a Molecular Explosive Moiety

机译：新型含分子炸药的高能环氧乙烷单体的合成与表征

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Energetic monomers with new design concept were synthesized for energetic prepolymers.Novel energetic monomers consisted of ring-oepning polymerizable oxirane and a molecular explosive moiety instead of small explosopores as energetic functional groups.According to the design concept, glycidyl dinitroazetidine (GDNAZ) and glyeidyl nitroazetidinol (GNAZO) energetic monomers were synthesized, respectively, and characterized by NMR, EA and GC MS.Heat of formation and detonation performance were calculated by theoretical method to evaluate energy performanee of these novel energetic monomers.The result revealed that GDANZ and GNAZO possessed high potential for use as new energetic monomers for synthesizing energetic prepolymers and binders in PBXs.

机译：为高能预聚物合成了具有新设计概念的高能单体，新颖的高能单体由环状的可聚合环氧乙烷和分子炸药部分组成，而不是由小的爆炸孔作为高能官能团。根据设计概念，缩水甘油基二硝基氮杂环丁烷（GDNAZ）和滑石基硝基氮杂环丁烷醇分别合成了（GNAZO）高能单体，并通过NMR，EA和GC MS对其进行了表征，并通过理论方法计算了它们的形成热和爆轰性能，以评价这些新型高能单体的能量性能。结果表明，GDANZ和GNAZO具有较高的能级。用作合成PBX中高能预聚物和粘合剂的新型高能单体的潜力。

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《Beijing Institute of Technology;China Ordnance Society;International autumn seminar on propellants, explosives and pyrotechnics;Hubei Institute of Aerospace Chemotechnology》|2015年|15-20|共6页
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MA Mingyang; LAN Qianqian; Younghwan KWON; Seunghyun CHANG; Jin Seuk KIM;
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中图分类爆炸物工业、火柴工业;
关键词
energetic monomer; dinitroazetidine; glycidyl dinitroazetidine;

机译：高能单体;二硝基氮杂环丁烷;缩水甘油基二硝基氮杂环丁烷;

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2. Characterization of High Explosives and Other Energetic Compounds by Computational Chemistry and Molecular Modeling. Experiments for the Undergraduate Curriculum [J] . John A. Bumpus, Anne Lewis, Corey Stotts, Journal of Chemical Education . 2007,第2期

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3. Synthesis of Stable and Soluble One-Handed Helical Homopoly(substituted acetylene)s without the Coexistence of Any Other Chiral Moieties via Two-Step Polymer Reactions in Membrane State: Molecular Design of the Starting Monomer [J] . Molecules . 2012,第1期

机译：通过膜态的两步聚合反应合成稳定且可溶的单手螺旋均聚（取代的乙炔）而没有其他手性部分的共存：起始单体的分子设计
4. Synthesis and Characterization of Novel Energetic Oxirane Monomers Containing a Molecular Explosive Moiety [C] . MA Mingyang, LAN Qianqian, Younghwan KWON, International autumn seminar on propellants, explosives and pyrotechnics . 2015

机译：含有分子爆炸部分的新型能量氧化乙烷单体的合成与表征
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7. Design and Synthesis of Novel Energetic Oxirane Monomers Containing a Molecular Explosive Moiety [O] . Yechen Shen, Younghwan Kwon, Jin Seuk Kim 2015

机译：设计和合成含有分子爆炸部分的新型能量氧化乙烷单体

Synthesis and Characterization of Novel Energetic Oxirane Monomers Containing a Molecular Explosive Moiety

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