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High-Performance Supercapacitors Based on Hierarchical VOx Microspheres Forming from Hyperbranched Nanoribbons

机译:基于超支化纳米带形成的分层VOx微球的高性能超级电容器

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Novel VOx nanomaterials as high performance electrode materials of supercapacitors were successfully synthesized by solvothermal method using V_2O_5, H_2O_2, (NH_4)_2SO_4 and EG (Ethylene Glycol). These as-prepared nanomaterials are hierarchical microspheres with diameter of ~5 μm, which formed from hyperbranched growth of nanoribbons. According to XRD and TEM, these hierarchical Vox microspheres consist of V_6O_(13) with metallic conductivity and VO_2. These materials exhibited a tremendous specific capacitance of 581 F/g, with corresponding volumetric specific capacitance of 3.94 F/cm~3, at 0.6 A/g in the potential range of 0 to 1.2 V when used as supercapacitor electrodes in a solution of 1 M LiNO_3. The energy density is as high as 29 Wh/kg, which is much higher than those of many other symmetrical supercapacitors. In addition, the capacity retention of 65% was achieved even after 2000 cycles, demonstrating high performance of vanadium oxide nanomaterials used in supercapacitors.
机译:采用V_2O_5,H_2O_2,(NH_4)_2SO_4和EG(乙二醇)通过溶剂热法成功合成了新型VOx纳米材料作为高性能超级电容器的电极材料。这些制备的纳米材料是直径约5μm的分层微球,由纳米带的超支化生长形成。根据XRD和TEM,这些分层的Vox微球由具有金属导电性和VO_2的V_6O_(13)组成。这些材料在1的溶液中用作超级电容器电极时,在0至1.2 V的电位范围内,在0.6 A / g的电势范围内显示出581 F / g的巨大比电容,相应的体积比电容为3.94 F / cm〜3 M LiNO_3。能量密度高达29 Wh / kg,远高于许多其他对称超级电容器的能量密度。此外,即使经过2000次循环,容量保持率也达到了65%,这证明了用于超级电容器的氧化钒纳米材料的高性能。

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