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Conceptual Kinetic Model of the Hydrogenotrophic Denitrification with Carrier Materials for Nitrate Removal

机译:氢脱硼酸氢脱氮的概念动力学模型,用于硝酸氢脱氮

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This research is focused on the kinetic model to enhance the hydrogen effectiveness in hydrogenotrophic denitrification (HD) with carrier materials. The modified two steps of Michaelis-Mention model were developed under two substrates limitation in batch test (initial nitrate and nitrite of 40-160 mg-N/L). The estimate values of the maximum specific growth rate, yield coefficient and half saturation constant were 0.0056 h~(-1), 19.22 mg/L and 1.44 mg-VS/mg-N for nitrate and 0.0032 h~(-1), 18.51 mg/L and 0.67 mg-VS/mg-N for nitrite, respectively. The maximum hydrogen gas capacity per biomass concentration was investigated and approximately 3.5 g-VS/1 g of H_2 gas was found in batch test. These above data were used to develop the modified model in continuous feeding (40 mg-N/L of nitrate) in the simple HD reactor with biologically carrier material. The modified continuous feed model was correlated with experimental data and useful for controlling the HD performance under lowest energy demand prediction. The system performance from lab-scale was shown to achieve exceptional nitrogen removal performance of 145.50 g/m~3/d with the highest hydrogen effectiveness of 454.70 mg-H_2/g-N.
机译:该研究专注于动力学模型,以增强具有载体材料的氢脱硝化(HD)中的氢气效力。在分批试验中的两个底物限制(初始硝酸盐和40-160mg-n / L的亚硝酸盐)下,在迈克利斯模型的修改了两步。最大特异性生长速率,产量系数和半饱和常数的估计值为0.0056h〜(-1),19.22mg / L和1.44mg-Vs / mg-n用于硝酸盐,0.0032小时〜(-1),18.51分别用于亚硝酸盐的Mg / L和0.67mg-Vs / mg-n。研究了每个生物质浓度的最大氢气容量,在分批测试中发现了约3.5g-Vs / 1g的H_2气体。这些上述数据用于在具有生物载体材料的简单HD反应器中在简单的HD反应器中在连续进料(40mg-N / L硝酸盐)中进行改性模型。修改的连续进料模型与实验数据相关,可用于控制最低能量需求预测下的高清性能。实验室标度的系统性能显示出卓越的氮去除性能为145.50克/ m〜3 / d,其氢效率最高为454.70mg-H_2 / G-n。

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