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One Hundred Percent Solids Ambient Cure Liquid Pipe Coating with Excellent Cathodic Disbondment Results

机译:百分之一百的固体环境固化液管道涂料,具有出色的阴极剥离性能

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Epoxy coatings have long been the work horse for Maintenance and Protective Coatings (M&PC) due to their excellent corrosion resistance, excellent heat and chemical resistance, good mechanical properties, as well as excellent adhesion to various substrates1. The epoxy resins are typically based on bisphenol A diglycidyl either (BADGE), bisphenol F diglycidyl either, and epoxy phenol novolacs2; and they are usually very viscous in nature and therefore require a high volume of solvent to reduce the viscosity for easier application. There is a strong desire among participants throughout the M&PC value chain to reduce the emission of volatile organic compounds (VOCs) from these coatings. One hundred percent solids coatings are one route to meet that objective. Olin Epoxy has designed a 100% solids formulated epoxy and hardener system to meet this need. This paper documents the performance of this system against a well-known commercial benchmark for external pipe coating applications. Fully pigmented two component liquid pipe coating formulas will be described and modifications of the formula to meet different volume mixing ratios will also be discussed. Various performance aspects of experimental and commercial benchmarks will be compared, including pot life, Konig hardness, low temperature curing performance, dry time, and cathodic disbondment (CD) at elevated temperatures. CD test results at dry film thickness (DFT) above 30 mils (750 microns) and less than 20 mils (500 microns) are also discussed. The range of conditions under which this high solids system can be applied to achieve good performance will also be summarized.
机译:环氧树脂涂料长期以来一直是维护和防护涂料(M&PC)的主力军,因为它们具有优异的耐腐蚀性,优异的耐热性和耐化学性,良好的机械性能以及对各种基材的优异附着力1。环氧树脂通常基于双酚A二缩水甘油基(BADGE),双酚F二缩水甘油基和环氧酚酚醛清漆2。而且它们通常性质上非常粘稠,因此需要大量的溶剂才能降低粘度,以使其易于使用。在整个M&PC价值链中,参与者强烈希望减少这些涂料中挥发性有机化合物(VOC)的排放。固含量为100%的涂料是实现该目标的一种途径。 Olin Epoxy设计了一种100%固体配方的环氧树脂和硬化剂系统,可以满足这一需求。本文根据外部管道涂层应用的著名商业基准记录了该系统的性能。将描述完全着色的两组分液体管道涂料配方,还将讨论该配方的修改以满足不同的体积混合比。将对实验和商业基准的各种性能方面进行比较,包括适用期,柯尼希(Konig)硬度,低温固化性能,干燥时间和高温下的阴极剥离(CD)。还讨论了干膜厚度(DFT)大于30密耳(750微米)且小于20密耳(500微米)时的CD测试结果。此高固含量体系可以应用以达到良好性能的条件范围也将进行总结。

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