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Experimental Study for the Development of Remote Sensing Technology of Hazardous Substances by Resonance Raman Effect

机译:共振拉曼效应发展有毒有害物质遥感技术的实验研究

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For Lidar technology that can identify the location of the target substances and measure spatial distribution, theestablishment of that technology is required so that it can comprehensively provide remote measuring hazardous substancesthat cause harm to human bodies, such as toxic substances and combustible substances. Hazardous substances exist in avery wide range of forms, for example, chemical species, physical conditions, and organisms or inorganisms. In addition,substances developed for the purpose of attacking the human body, represented by nerve agents, exhibit their effects by asmall amount. Therefore, in order to realize remote sensing of hazardous substances, it is necessary to apply an excellentmeasurement principle that can respond to the diversity and the detection of trace components of these objects.The Raman effect is a useful phenomenon that enables identification of many individual substances, but the extremelyweak response has led to significant limitations in applicable fields. In this study, we conducted basic experiments for therealization of remote sensing technology of hazardous substances based on the resonance Raman effect.The resonance Raman effect is a phenomenon in which the intensity of Raman scattering light is greatly enhanced byexcitation with light of a wavelength corresponding to the electronic transition energy of the target substance. The presenceof electronic transition energy of substances can be confirmed by observing the ultraviolet absorption spectra. Manyhazardous substances exhibit ultraviolet absorption in the deep ultraviolet wavelength region of 300 nm or less. Therefore,in this study, we constructed a resonance Raman spectrum measuring device capable of wavelength sweeping in the deepultraviolet wavelength range, selected SO2 and NH3, typical corrosive gases, as target substance, and verifiedexperimentally the enhancement of Raman signal intensity by resonance Raman effect.
机译:对于可识别目标物质的位置并测量空间分布的LIDAR技术, 需要建立该技术,以便全面提供远程测量危险物质 对人体造成伤害,如有毒物质和可燃物质。存在危险物质 非常广泛的形式,例如化学品种,物理条件和生物体或无机症。此外, 为攻击人体而开发的物质,由神经药物代表,表现出它们的影响 少部分。因此,为了实现有害物质的遥感,有必要应用优异的 测量原理,可以响应多样性和这些物体的跟踪组件的检测。 拉曼效应是一种有用的现象,可以识别许多单独的物质,但是极端 弱响应导致适用领域的显着限制。在这项研究中,我们对此进行了基本实验 基于共振拉曼效应的危险物质遥感技术实现。 共振拉曼效果是一种现象,其中拉曼散射光的强度大大提高了 用与目标物质的电子转变能量对应的波长的光激发。存在 通过观察紫外线吸收光谱,可以确认物质的电子转换能量。许多 危险物质在300nm或更小的深紫外波长区域中表现出紫外线吸收。所以, 在这项研究中,我们构建了一种能够在深处清扫波长的共振拉曼频谱测量装置 紫外线波长范围,选择SO2和NH3,典型的腐蚀性气体,作为靶物质,并验证 通过实验通过共振拉曼效应提高拉曼信号强度。

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