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Controlling the Luminescence of Gold Quantum Dots by the Plasmonic Effect of Silver Nanoprisms

机译:通过银纳米棱镜的等离子体效应控制金量子点的发光

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The fluorescent resonance energy transfer (FRET) has been paid great attention and utilized for developing fluorescence sensors,which have great sensitivity and simple detection method. In this work, we are interested in fluorescent quenching effect using thelocalized surface plasmon resonance (LSPR) of plasmonic material. Silver nanoprisms (AgNPrs) were used as an acceptor, whereasgold quantum dots (AuQDs) were used as a donor. The distance and the overlapping energy between those materials, which affectedFRET, was investigated. We functionalized the surface of AgNPrs with two different length of dithiol molecules, which were 1, 6-hexanedithiol and 1, 8-octanedithiol. The maximum fluorescent quenching of AuQDs binding with dithiol-functionalized AgNPrsreached to 72 %. The results exhibited great potential for wide application of fluorescence sensor.
机译:荧光共振能量转移(FRET)已引起广泛关注,并被用于开发荧光传感器, 灵敏度高,检测方法简单。在这项工作中,我们对使用 等离子体材料的局部表面等离子体共振(LSPR)。银纳米棱镜(AgNPrs)被用作受体,而 金量子点(AuQDs)被用作施主。这些材料之间的距离和重叠能量影响了 FRET,进行了调查。我们用两种不同长度的二硫醇分子(分别为1、6- 己二硫醇和1,8-辛二硫醇。与二硫醇官能化的AgNPrs结合的AuQD的最大荧光猝灭 达到72%。该结果显示了荧光传感器的广泛应用的巨大潜力。

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