On S/sub 2/F/sub 10/ formation in spark breakdown of SF/sub 6/

机译：在S / sub 2 / f / sub 10 / sf / sub 6的SIALL BREAKDOWN中/

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The authors report on the gas chromatographic (GC) analyses of sparked SF/sub 6/ and the comparison with the analyses of 0.5% S/sub 2/F/sub 10//SF/sub 6/ mixtures. Under the GC conditions used, a peak is observed at elution times identical (to within 0.8%) to the S/sub 2/F/sub 10/ peak in the S/sub 2/F/sub 10//SF/sub 6/ samples. Measurements made on SO/sub 2//SF/sub 2//SF/sub 6/ mixtures indicate that SO/sub 2/ elutes from the column at times extremely close to but slightly longer (by 10%) than what is believed to be the S/sub 2/F/sub 10/ peak. Although complete confirmation of the identification of S/sub 2/F/sub 10/ in the sparked SF/sub 6/ samples awaits further measurements by mass spectrometry of the GC effluent, these analyses indicate that S/sub 2/F/sub 10/ is formed in amounts (on the order of hundreds of p.p.m.) consistent with concentrations necessary for producing the toxic effects previously observed.

机译：作者报告了引发的SF / sub 6的气相色谱（GC）分析，以及与0.5％S / SUB 2 / S亚10 // SF / SUB 6 /混合物的分析的比较。在所用的GC条件下，在S / SUB 2 / F / SUB 10 / SF / SUB 6中的S / SUB 2 / F / SUP 10 /峰值中在溶液时间（至0.8％）的洗脱时间（至0.8％以内）观察峰值/样品。在SO / SUB 2 // SF / SUB 2 // SF / SUB 6 /混合中的测量表明，所以如此/亚2 /从柱子中的拍摄时的时间非常接近但稍长（达到10％）而不是所迈出的是S / SUB 2 / F / SUB 10 /峰值。虽然完全确认S / sub 2 / s亚的鉴定/在引发的SF / sub 6 /样品中，但是通过GC流出物的质谱法进一步测量，但这些分析表明S / SUB 2 / F / SUB 10 /以与产生先前观察到的毒性效应所需的浓度一致的量（大约数百ppm）形成。

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《IEEE International Symposium on Electrical Insulation》|1988年||共4页
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Sauers I.; Votaw P.C.; Institute of Electric and Electronic Engineer;
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中图分类自动化技术、计算机技术;
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机译：S _{2 f _{10 ，s _{2 的_{10 ，以及s _{2 O _{2 f _{10 从SF _{6 和sf _{6 / o _{中的火花和负电晕放电2 气体混合物}}}}}}}}}}
11. S sub 2 F sub 10 Formation in Spark Breakdown of SF sub 6 [R] . Sauers, I. , Votaw, P. C. , Griffin, G. D. , 1988

机译：s sub 2 F sub 10在sF sub 6的spark Breakdown中的形成

On S/sub 2/F/sub 10/ formation in spark breakdown of SF/sub 6/

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