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LOW-COST FABRICATION PROCESS FOR YSZ ELECTROLYTE FILMS

机译:YSZ电解质薄膜的低成本制造工艺

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NexTech Materials is collaborating with Siemens Westinghouse on the development of a low-cost electrolyte deposition process to replace electrochemical vapor deposition for the Siemens Westinghouse tubular SOFC. The approach being pursued involves preparation of a dispersed suspension of nanoscale yttrium-stabilized zirconia (YSZ) crystallites, deposition of green YSZ electrolyte films onto lanthanum manganite (LSM) cathode tubes, and sintering of the deposited YSZ films to full density. A hydrothermal synthesis process is being used to prepare the nanoscale YSZ suspensions, and process enhancements have been made to achieve nearly complete dispersion of the YSZ crystallites in aqueous suspensions. Simple dip coating and spray coating methods are being used to deposit YSZ electrolyte films from the dispersed suspensions onto LSM tube sections. With suitable modifications to the suspension chemistry and deposition methods, sintered YSZ films have been prepared that are continuous and crack-free. Efforts also are underway to scale up the YSZ synthesis process using a novel continuous reactor system. NexTech's recent progress on this program is described in this paper.
机译:Nextech Materials与西门子西屋进行合作开发了低成本电解质沉积过程,以替换西门子西屋管状SOFC的电化学气相。正在追求的方法包括制备纳米级钇稳定的氧化锆(YSZ)微晶的分散悬浮液,将绿色YSZ电解质膜沉积到镧锰锰酯(LSM)阴极管上,并将沉积的YSZ薄膜烧结至全密度。使用水热合成方法用于制备纳米级YSZ悬浮液,已经进行了方法,以实现YSZ微晶在含水悬浮液中的几乎完全分散。简单的浸涂和喷涂方法用于将YSZ电解质薄膜从分散的悬浮液沉积到LSM管部分上。通过对悬浮化学和沉积方法的合适修饰,已经制备了烧结的YSZ薄膜,其是连续和无裂缝的。还可以使用新型连续反应堆系统来扩大YSZ合成过程的努力。 Nextech在本文中描述了该程序的最新进展。

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