INFLUENCE OF NOBLE METALS ON THE PERFORMANCE OF Co/SiO_2 CATALYST FOR 1-HEXENE HYDROFORMYLATION

机译：贵金属对1-己烯加氢甲酰化Co / SiO_2催化剂性能的影响

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

Small amount of Pt, Pd and Ru promoters in Co/SiO_2 led to great improvement of catalyst activity for hydroformylation of 1-hexene. The 1-hexene conversion as high as 89.7% and oxygenate products selectivity of 88.9% were obtained after 2 h reaction on Pd promoted Co/SiO_2 catalyst. The increasing of reduction degree, the minimizing of cobalt particle size and the enhancement of carbonyl and linear CO adsorption were responsible for the improved performance of the catalyst.

机译：CO / SiO_2中的少量Pt，Pd和Ru启动子导致了1-己烯加氢甲酰化催化剂活性的大量改善。在Pd促进Co / SiO_2催化剂的2小时后，得到了高达89.7％和含氧产物的1-己烯转化率为88.9％的选择性。降低程度的增加，最小化钴粒径和羰基和线性Co吸附的增强负责催化剂的改善性能。

著录项

来源
《China-Japan symposium on coal and C1 chemistry》|2001年||共4页
会议地点
作者
Xianqing Qiu; Shouli Sun; Noritatsu Tsubaki; Kaoru Fujimoto;
展开▼
作者单位

展开▼
会议组织
原文格式 PDF
正文语种
中图分类 TK433.6;
关键词
hydroformylation; 1-hexene; supported cobalt catalyst; noble metal;

机译：加氢甲酰化;1-己烯;支持的钴催化剂;贵金属;

相似文献

外文文献
中文文献
专利

1. Hydroformylation of 1-Hexene over Co/Sio_2 Catalysts: Influence of Pore Size of Support [J] . XianQing Qiu, Noritatsu Tsubaki, Kaoru Fujimoto Journal of Chemical Engineering of Japan . 2001,第11期

机译：Co / Sio_2催化剂上1-己烯的加氢甲酰化：载体孔径的影响
2. Low-pressure hydroformylation of 1-hexene over active carbon-supported noble metal catalysts [J] . Zhang Y, Nagasaka K, Qiu XQ, Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2004,第1a2期

机译：活性炭负载贵金属催化剂上1-己烯的低压加氢甲酰化
3. Low-pressure hydroformylation of 1-hexene over active carbon-supported noble metal catalysts [J] . Yi Zhang, Keisukje Nagasaka, Xianqing Qiu, Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2003,第1a2期

机译：活性炭负载贵金属催化剂上1-己烯的低压加氢甲酰化
4. INFLUENCE OF NOBLE METALS ON THE PERFORMANCE OF Co/SiO_2 CATALYST FOR 1-HEXENE HYDROFORMYLATION [C] . Xianqing Qiu, Shouli Sun, Noritatsu Tsubaki, The 7th China-Japan symposium on coal and C1 chemistry proceedings . 2001

机译：贵金属对1-己烯加氢甲酰化Co / SiO_2催化剂性能的影响
5. Processing-structure-property studies of: (I) submicron polymeric fibers produced by electrospinning and (II) films of linear low density polyethylenes as influenced by the short chain branch length in copolymers of ethylene/1-butene, ethylene/1-hexene and ethylene/1-octene synthesized by a single site metallocene catalyst. [D] . Gupta, Pankaj. 2004

机译：加工结构性质的研究：（I）受乙烯/ 1-丁烯，乙烯/ 1-己烯和乙烯共聚物的短支链长度影响的线性纺丝生产的亚微米聚合物纤维和（II）线性低密度聚乙烯薄膜单中心茂金属催化剂合成的乙烯/ 1-辛烯。
6. CeO2 nanowires self-inserted into porous Co3O4 frameworks as high-performance noble metal free hetero-catalysts [O] . Xiao Wang, Shuna Zhao, Yibo Zhang, 2016

机译：CeO2纳米线作为高性能的无贵金属杂催化剂自插入多孔的Co3O4骨架中
7. Operando High-Pressure NMR and IR Study of the Hydroformylation of 1-Hexene by 1, 1-Bis(Diarylphosphino)metallocene-Modified Rhodium(I) Catalysts [O] . -1

机译：Operando高压NMR和IR研究1-己烯的加氢甲酰化1-双（二芳基膦铝）茂金属改性的铑（I）催化剂
8. Rhenium Catalysis:Ⅰ. Hydrogenation and Hydroformylation Using Rhenium Carbonyl Compounds. Ⅱ. Hydrogenation Using Catalysts Obtained from the Reduction of Perrhenates with Metals in Aqueous Solution [R] . T. G. Selin 1957

机译：铼催化：Ⅰ。使用铼羰基化合物进行氢化和加氢甲酰化。 Ⅱ。在水溶液中用金属还原高铼酸盐获得催化剂的氢化

INFLUENCE OF NOBLE METALS ON THE PERFORMANCE OF Co/SiO_2 CATALYST FOR 1-HEXENE HYDROFORMYLATION

摘要

著录项

相似文献

相关主题

期刊订阅