Thermal conductivity of M-Si-N (M = Mg, Ca, Sr, Ba) compounds with varying M/Si ratio

机译：具有不同M / Si比的M-Si-N（M = Mg，Ca，Sr，Ba）化合物的热导率

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The thermal conductivity of M-Si-N (M = Mg, Ca, Sr, Ba) compounds is reviewed. The emphasis is on MgSiN_2 (a material which can be derived from A1N by replacing systematically 2A1~(3+) by Mg~(2+)/Si~(4+)), and Si_3N_4 (the well knownβ-modification as well as the recently discovered cubic modification with the spinel structure). In addition the processing, characterisation and thermal conductivity of novel ceramic M-Si-N materials with an M/Si ratio lower than 1 are dealt with. The measured thermal conductivity is compared with estimations of maximum achievable values, and the relation with network connectivity is discussed.

机译：综述了M-Si-N（M = Mg，Ca，Sr，Ba）化合物的导热率。重点是Mgsin_2（通过系统上通过Mg〜（2 +）/ Si〜（4+）和Si_3N_4（众所周知的β修改以及众所周知的β-修改以及众所周知的β-修改，可以通过A1N衍生自A1N的材料）最近发现了用尖晶石结构的立方体修改）。此外，新型陶瓷M-Si-N材料的处理，表征和导热性具有低于1的m / si比。将测量的导热率与最大可达到的值的估计进行比较，并且讨论了与网络连接的关系。

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《Conference exhibition of the European Ceramic Society》|2002年||共4页
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H.T. Hintzen; R.J. Bruls; A.C.A. Delsing; K. Itatani; S. Tanaka; G. de With; R. Metselaar;
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中图分类玻璃、陶瓷;
关键词
nitride; alkaline-earth; silicon; ceramics; thermal conductivity;

机译：氮化物;碱土;硅;陶瓷;导热率;

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Thermal conductivity of M-Si-N (M = Mg, Ca, Sr, Ba) compounds with varying M/Si ratio

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