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Non-catalyst and low temperature growth of vertically aligned carbon nanotubes for nanosensor arrays

机译:用于纳米传感器阵列的垂直取向碳纳米管的非催化剂和低温生长

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In this paper we present a new technique to vertically grow aligned carbon nanotubes (CNTs) on nanosize pore anodic aluminum oxide (AAO) templates on a Si substrate. The CNTs are grown using methane in an RF PECVD system at only 400/spl deg/C without using a transition metal catalyst. The AAO templates are prepared by a two-step anodizing process in oxalic acid at room temperature. The influence of preparation conditions, such as temperature, electrolyte, applied voltage and anodization time on the density, diameter, length and the shape of the pores is investigated. The diameter of the pores of AAO film varies from 30 nm to 70 nm. The average diameter and length of CNTs are approximately 40 nm and 1 /spl mu/m respectively. This low temperature, IC-compatible process is very attractive as it allows integration of CNT devices with on-chip electronics.
机译:本文介绍了一种新的技术在Si衬底上垂直于垂直于垂直于纳米孔阳极氧化铝(AAO)模板上的对齐的碳纳米管(CNT)。使用过渡金属催化剂,仅在RF PECVD系统中使用甲烷在RF PECVD系统中生长。 AAO模板通过在室温下在草酸中的两步阳极氧化方法制备。研究了制备条件的影响,例如温度,电解质,施加的电压和阳极氧化时间对孔的密度,直径,长度和形状的密度,直径,长度和形状。 AaO膜的孔的直径在30nm至70nm之间变化。 CNT的平均直径和长度分别为约40nm和1 / spl mu / m。这种低温,IC兼容的过程非常有吸引力,因为它允许将CNT器件集成到片上电子器件。

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