ENTHALPIES OF FORMATION OF RADICALS OF THE NITRODERIVATIVES METHANE

机译：硝基酸甲烷的自由基形成焓

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On the basis of complex thermochemical researches, check experiments and literary data are chosen and the enthalpies of formation of the nitroderivatives of a methane in standard and gaseous condition are recommended. The established laws of interaction of nitrogroups in the specified compounds in aggregate with data on the kinetics of their thermal disintegration have allowed to recommend the most reliable values of energies of a dissociation of bonds C - NO_2. The received values have enabled to receive the appropriate enthalpies of formation of the ni-tromethyl radicals and energy of a dissociation C - H of bonds. It shown, that the energies of a dissociation C - H of bonds practically do not depend on quantity of nitrogroups connected to atoms of carbon, as well as in the halogenderivatives of the methane. The enthalpies of formation of radicals CH_2NO_2~·, CH(NO_2)_2~·, C(NO_2)_3~·, CHNO_2~(··), C(NO_2)_2~(··) and CNO_2~(···) are designed, and the energies of a dissociation NO_2 of groups from radicals of the nitroderivative of a methane are designed.

机译：在复杂的热化学研究的基础上，选择检查实验和文学数据，建议使用标准和气态条件下甲烷的硝基酸的形成焓。在总体崩解的动力学中，将指定化合物中的NITrogroups与其热崩解动力学的统一律法允许推荐最可靠的键C - NO_2的能量的能量值。所接收的值使得能够接收形成Ni-Tromethyl自由基的适当焓和解离C - H的粘合剂的能量。图3所示，解离C-H的能量实际上不依赖于连接到碳原子的硝基聚合物的量，以及甲烷的卤代体。基团形成的焓CH_2NO_2〜·，CH（NO_2）_2〜·，C（NO_2）_3〜·，CHNO_2〜（··），C（NO_2）_2〜（··）和CNO_2〜（···设计了设计，设计了来自甲烷的氮衰有的基团的分离NO_2的能量。

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《International Annual Conference of ICT》|2005年||共7页
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ENTHALPIES OF FORMATION OF RADICALS OF THE NITRODERIVATIVES METHANE

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