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DISPERSION AND FLUIDITY OF AQUEOUS ALUMINIUM TITANATE SLURRY BY ADDITION OF TITANATE AQUEOUS SOLUTION

机译:加入钛酸盐水溶液水溶液水溶液的分散和流动性

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A water soluble titanate compound (TNB Lac) prepared by direct reaction of titanium tetra n butoxide (TNB) with lactic acid (Lac) in water showed characteristics of a polyanion and acted as a dispersant for preparing aqueous aluminum titanate (Al_2TiO_5) slurries. The isoelectric point of Al_2TiO_5 particles shifted to lower pH with increasing concentration of TNB Lac. The Theological behavior of aqueous Al_2TiO_5 slurries with TNB Lac was examined and evaluated. The dispersion and fluidity of aqueous Al_2TiO_5 slurry were enhanced by the addition of TNB Lac at pH 10, and the thickening limit of the well dispersed and fluidized slurry with 0.075 mmol g~(-1) TNB Lac was found at a solid content of 79 wt%. A high green density of 63% for the sintered powder was obtained through the slip casting process using slurries with 0.075 mmol g~(-1) TNB Lac. The maximum relative density value of the sintered bodies was 96.5% when the green body was fired at 1500°C. The sintered body had a homogeneous grain growth and dense microstructure without pores or abnormal grain growth.
机译:一种水溶性钛酸盐化合物(TNB LAC)制备通过用乳酸(LAC)的水钛,四正丁醇(TNB)的直接反应显示出聚阴离子的特性和充当用于制备含水钛酸铝(Al_2TiO_5)浆料的分散剂。 Al_2TiO_5颗粒的等电点偏移到较低的pH值随着TNB紫胶的浓度。检查和评价含水Al_2TiO_5浆料用TNB紫胶的流变行为。分散体和水性Al_2TiO_5浆料的流动性通过加入TNB紫胶在pH 10增强,并且很好地分散和流化床浆液的增稠限制用0.075毫摩尔克〜(-1)TNB紫胶被发现在79的固体含量重量%。通过使用浆料滑移浇铸过程与0.075毫摩尔克〜(-1)TNB紫胶获得的63%的烧结粉末的高的生坯密度。的烧结体的最大相对密度值为96.5%时的生坯在1500℃下烧制。烧结体具有均匀的晶粒生长和组织致密无气孔或异常晶粒生长。

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