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Preparation and characteristics of Aziridine-Benzoguanamine-Urea-Melanmine-Formaldehyde resins

机译:氮素 - 苯并胍胺 - 脲 - 甲甲甲醛树脂的制备及特征

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In this study, the effect of Aziridine (AZ) addition on the properties of the BG-MF and BG-U-MF resin, such as the mechanical strength, tensile strength, moisture adsorption, and limited oxygen index, were studied in details. The best performance was obtained for modified resins with 2 wt. % added AZ. The structure characteristics of the modified MF resins were investigated using Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). It was found that the characteristic absorption peak of the hydroxyl group and the ring of the three triazine group was significantly reduced, which indicated that the addition of aziridine was beneficial to the curing reaction. It could be seen that the effect of the addition of aziridine on the crystallinity of BG15% modified resin was not obvious, but the crystallinity of BG15%+U20% modified resin was reduced. The tensile strength and elongation at break increased after the addition of 2% aziridine, and resistance to burning and boiling water were also improved.
机译:在本研究中,详细研究了偶氮(AZ)添加对BG-MF和BG-U-MF树脂的性质的影响,例如机械强度,拉伸强度,水分吸附和有限的氧指数。为2重量%的改性树脂获得了最佳性能。 %添加了az。使用傅里叶变换红外光谱(FTIR)和X射线衍射(XRD)研究改性MF树脂的结构特征。发现羟基的特征吸收峰和三个三嗪基团的环显着降低,这表明加入氮啶有利于固化反应。可以看出,加入氮化辛对B15%改性树脂的结晶度的影响不明显,但BG15%+ U20%改性树脂的结晶度降低。在加入2%的氮啶后,断裂的拉伸强度和伸长率也增加,并且还改善了对燃烧和沸水的抗性。

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