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首页> 外文会议>Conference on Organic Photonic Materials and Devices >Coordination-driven self-assembly of multi-chromophoric architectures using photoactive building blocks
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Coordination-driven self-assembly of multi-chromophoric architectures using photoactive building blocks

机译：使用光活性构建块协调驱动多发色体架构的自组装

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Coordination-driven self-assembly is a synthetic method that uses metal-ligand bonding as the driving force for the formation of polynuclear metallacycles and cages. These discrete molecules may exhibit so-called emergent properties, wherein the proximity of building blocks results in novel electronic structure and related photophysical properties. Self-assembly reactions using iridium complexes as metal nodes and organic molecules as linkers generates a library of metallacycles and cages containing multiple chromophores. These architectures preserve the promising photochemistry of the monomeric Ir centers found at the nodes in the context of organic light-emitting diodes and non-linear optical applications such as reverse saturable absorption. The design and characterization of a small library of platinum and iridium assemblies is presented with an emphasis on understanding the differences between the properties of the independent building blocks and those of the assemblies.
机译：协调驱动的自组装是一种合成方法，其使用金属配体键合作为形成多核金属间母标和笼的驱动力。 这些离散分子可以表现出所谓的泌喷性能，其中构建块的附近导致新颖的电子结构和相关的光药性。 作为接头的使用铱配合物作为金属节点和有机分子的自组装反应产生含有多个发色团的金属间母梗和笼子文库。 这些架构保留了在有机发光二极管和非线性光学应用的节点中发现的诸如反向可饱和吸收的非线性光学应用中的节点中发现的高级射程的有希望的光化学。 提出了一个小铂和铱组件图书馆的设计和表征，并强调了解独立构建块的性质与组件之间的性质之间的差异。

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