Novel Reaction Scheme for the Selective Oxidation of o-Xylene to Phthalic Anhydride

机译：将O-二甲苯选择氧化成邻苯二甲酸酐的新型反应方案

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The oxidation of o-xylene to phthalic anhydride is one of the important industrial processes based on selective oxidation reactions. For the last 50 years vanadia - titania catalysts have been used in this process. The reaction parameters like temperature range of operation, reactor inlet pressure, contact time, etc. slightly changed during this continuous process optimization. However, the fundamental understanding of the byproduct formation is still an open task. By using a sample port pilot plant, a detailed investigation was conducted for the first time of the by-product formation at different operation conditions. Several hitherto unknown intermediates could unambiguously be identified. The combination of process conditions and by-product formation enables the discussion of a new improved reaction scheme for the catalytic oxidation of o-xylene.

机译：O-二甲苯氧化成邻苯二甲酸酐是基于选择性氧化反应的重要工业过程之一。在过去50年中，vanadia - 钛菊催化剂已被用于该过程中。反应参数如操作温度范围，反应器入口压力，接触时间等在该连续过程优化期间略有变化。然而，对副产品形成的根本了解仍然是一个开放的任务。通过使用样品端口先导工厂，在不同操作条件下进行副产物形成的第一次进行详细的研究。几个迄今为止未知的中间体可以明确识别。工艺条件和副产物形成的组合能够讨论用于O-二甲苯的催化氧化的新改进的反应方案。

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《International conference on chemical and process engineering》|2011年||共6页
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Robert Marx; Hans-Joerg Woelk; Gerhard Mestl; Thomas Turek;
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中图分类化学反应过程;
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1. V_2O_5-ZrO_2 catalyst for selective oxidation of o-xylene to phthalic anhydride:I. Catalyst preparation, catalytic activity and selectivity measurements [J] . L. Makedonski Bulgarian chemical communications: Journal of the Chemical Institutes of the Bulgarian Academy of Sciences and of the Bulgarian Chemical Society . 2009,第3期

机译：用于将邻二甲苯选择性氧化为邻苯二甲酸酐的V_2O_5-ZrO_2催化剂：催化剂制备，催化活性和选择性测量
2. The effect of cesium and antimony promoters on the performance of Ti-phosphate-supported vanadium(V) oxide catalysts in selective oxidation of o-xylene to phthalic anhydride [J] . Akbari A., Alavi S. M. Chemical Engineering Research & Design: Transactions of the Institution of Chemical Engineers . 2015,第Octa期

机译：铯和锑促进剂对钛磷酸盐负载的钒（V）氧化物催化剂在邻二甲苯选择性氧化成邻苯二甲酸酐中的性能的影响
3. Selective oxidation of o-xylene to phthalic anhydride on tungsten, tin, and potassium promoted VOx on TiO2 monolayer catalysts [J] . Eversfield P., Lange T., Hunger M., Catalysis Today . 2019,第期

机译：TiO2单层催化剂上钨，锡和钾促进钨酸酐对邻苯二甲酸酐的选择性氧化
4. Novel Reaction Scheme for the Selective Oxidation of o-Xylene to Phthalic Anhydride [C] . Robert Marx, Hans-Joerg Woelk, Gerhard Mestl, 10th international conference on chemical and process engineering . 2011

机译：邻二甲苯选择性氧化为邻苯二甲酸酐的新型反应方案
5. An investigation of active and selective oxygen in vanadium phosphorus oxide catalysts for n-butane conversion to maleic anhydride [D] . Lashier, Mark Edward 1989

机译：钒磷氧化物催化剂中将正丁烷转化为顺丁烯二酸酐的活性氧和选择性氧的研究
6. Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts [O] . Jong Yeob Jeon, Seong Chan Eo, Jobi Kodiyan Varghese, 2014

机译：使用（salen）Co（III）配合物将四种季铵盐束缚在一起实现二氧化碳/环氧丙烷/邻苯二甲酸酐的共聚和三元聚合
7. Kinetics of the selective oxidation of o-xylene to phthalic anhydride [O] . Marx Robert 2013

机译：邻二甲苯选择性氧化为邻苯二甲酸酐的动力学
8. Selective Oxidation of n-Butane to Maleic Anhydride over Model Vanadium-Phosphorus Oxide Catalysts [R] . Moser, T. P. 1985

机译：用模型钒 - 磷氧化物催化剂选择性氧化正丁烷制备马来酸酐

Novel Reaction Scheme for the Selective Oxidation of o-Xylene to Phthalic Anhydride

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