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Proton conduction in electrolyte made of manganese dioxide for hydrogen gas sensor

机译:用于氢气传感器的二氧化锰制成的电解液中的质子传导

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We propose a network model of oxygen-pairs to store and conduct protons on the surface of manganese dioxide with a weak covalent bond like protons stored in pressured ice. The atomic distances of oxygen-pairs were estimated between 2.57 and 2.60 angstroms in crystal structures of ramsdellite-type and lambda-type manganese dioxides by using protonated samples and inelastic neutron scattering measurements. Good properties for a hydrogen gas sensor using electrolytes made of manganese dioxides that contain such oxygen-pairs were confirmed experimentally.
机译:我们提出了一种氧合对的网络模型,以在二氧化碳表面上存储和传导质子,其具有弱的共价键,如质子储存在加压的冰上。 通过使用质子化样品和非弹性中子散射测量,估计氧型和λ型二氧化氧化物的晶体结构的2.57和2.60埃的原子距离。 通过实验证实了使用由含有这种氧对的二氧化氧化锰制成的电解质的氢气传感器的良好性能。

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