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Thermodynamic Analysis for the Pressure Effects on Reforming Reaction of Methane Wet-air at Low Temperature in a Micro-reactor

机译:微反应器低温下甲烷湿空气重整反应的压力效应的热力学分析

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How to keep combustion stability and less carbon deposit in micro-channel for the methane wet-air auto-thermal reforming combustion technology is a hot research area all over the world now. Even if there are some literatures with respect to this area, but there are many problems to keep studying. In this paper, the effects on the carbon deposit rule, hydrogen and methane conversion characteristics under lean oxygen at pressure have been studied below 973K by thermodynamic analysis with constant feed gas mass flow. Results show that the carbon deposit increases with increasing the temperature first, and then, it decreases. At the same time, the carbon deposit always decreases with increasing reaction pressure. At the different reaction pressure, the temperature zone of carbon deposit is changed, but the upper temperature limit is around 850K. H_2 mass fraction and CH_4 conversion ratio are raised with increasing the temperature, decreased with increasing the pressure. Adding pressure helps to reduce carbon deposit and maintain a certain H_2 mass fraction and CH_4 conversion ratio. All results show the reasonable reaction pressure is 0.2MPa in micro reactor.
机译:如何保持燃烧稳定性和较少的碳沉积物在微通道中用于甲烷湿空气自动热改装燃烧技术是现在全世界的热门研究区。即使有一些关于这一领域的文献,但还有很多问题要继续学习。本文通过恒定进料气体质量流动研究,在973K下,研究了对压力下贫氧下碳沉积规律,氢气和甲烷转化特性的影响。结果表明,碳沉积物首先增加温度,然后减少。同时,碳沉积物随着反应压力的增加而始终降低。在不同的反应压力下,碳沉积物的温度区变化,但上温限量约为850K。随着温度的增加,H_2质量分数和CH_4转化率升高,随着压力的增加而降低。添加压力有助于减少碳沉积物并保持某种H_2质量分数和CH_4转化率。所有结果表明,微反应器中合理的反应压力为0.2MPa。

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