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The Thermodynamics of Slag Forming Inorganic Phases in Biomass Combustion Processes

机译：生物质燃烧过程中炉渣形成无机阶段的热力学

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摘要

To reduce the use of fossil fuels and increase self-sufficiency in energy, nowadays, there is an increasing interest to produce heat, power and transportation fuels from renewable resources. Solid biomass is one of the most important renewable energy sources for meeting this target. However, fouling, slagging, and corrosion threaten long-term operation availability and costs of biomass power plants. Slags accumulated on the surfaces of superheaters, which decrease thermal efficiency, often constitute a considerable percentage of complex inorganic phases. However, thermodynamic properties of the complex inorganic phases and their combined effect, which will help to deal with the slag related problems during high-temperature biomass combustion processes, are not well known. In the present paper, thermodynamic properties of K-, Ca-, and Na-based inorganic phases and their mixtures under different gas conditions are both critically reviewed and experimentally studied. The obtained results are presented and discussed.
机译：为减少化石燃料的使用并提高能源的自给自足，现在，增加可再生资源的热量，电力和运输燃料的兴趣越来越兴趣。固体生物质是满足该目标的最重要的可再生能源之一。然而，污垢，粘接和腐蚀威胁到生物质发电厂的长期运行可用性和成本。累积在过热剂表面上的炉渣，降低热效率，通常构成相当大的复杂无机阶段。然而，复杂无机阶段的热力学性质及其组合效应，这将有助于在高温生物量燃烧过程中处理渣相关问题，是不公知的。在本文中，在不同气体条件下K-，Ca和Na基无机阶段的热力学性质及其混合物均批评和实验研究。提出并讨论了所得结果。

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