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首页> 外文会议>International Conference on Construction, Architecture and Technosphere Safety >Mechanisms for Reduction of Natural Waters Technogenic Pollution by Metals due to Complexions with Humus Substances (Zoning: Western Siberia and the European Territory of Russia)
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Mechanisms for Reduction of Natural Waters Technogenic Pollution by Metals due to Complexions with Humus Substances (Zoning: Western Siberia and the European Territory of Russia)

机译：由于腐殖质物质的肤色肤色，金属对天然水促进的机制（分区：西西伯利亚和俄罗斯欧洲领土）

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The article described the complexation of metal ions with humus substances in natural waters (small lakes). Humus substances as the major biochemical components of natural water have a significant impact on the forms and migration of metals and the toxicity of natural objects. This article presents the results of large-scale chemical experiments: the study of the structural features (zonal aspects) of humus substances extracted from soil and water natural climatic zones (more than 300 objects) in Russia (European Russia and West Siberia); the influence of structural features on the physic-chemical parameters of humus acids and, in particular, on their complexing ability. The functional specifics of humus matter extracted from soils is estimated using spectrometric techniques. The conditional stability constants for Fe(III), Cu(II), Pb(II), Cd(II), Zn(II), Ni(II), Co(II), Mn(II), Cr(III), Ca(II), Mg(II), Sr(II), and Al(III) are experimentally determined with the electrochemical, spectroscopic analysis methods. The activities of metals are classified according to their affinity to humus compounds in soils and water. The determined conditional stability constants of the complexes are tested by model experiments, and it is demonstrated that Fe and Al ions have higher conditional stability constants than the ions of alkali earth metals, Pb, Cu, and Zn. Furthermore, the influence of aluminium ions and iron on the complexation of copper and lead as well as the influence of lead and copper on complexation of cobalt and nickel have been identified. The metal forms in a large number of lakes are calculated basing on the experiments' results. The main chemical mechanisms of the distribution of metals by forms in the water of the lakes in European Russia and West Siberia are described.
机译：该文章描述了金属离子与天然水域中的腐殖质物质（小湖泊）的络合。腐殖质物质作为天然水的主要生化成分对金属的形式和迁移和自然物体的毒性产生了重大影响。本文介绍了大规模化学实验的结果：腐殖质物质（俄罗斯俄罗斯和西西伯利亚）从土壤和水自然气候区（超过300个物体）中提取的腐殖质物质（禽畜）的结构特征（带状方面）的研究;结构特征对腐殖质酸性物理学参数的影响，尤其是络合能力。利用光谱技术估计从土壤中提取的腐殖质物质的功能细节。 Fe（III），Cu（II），Pb（II），CD（II），Zn（II），Ni（II），CO（II），Mn（II），Cr（III），通过电化学，光谱分析方法实验确定Ca（II），Mg（II），Sr（II）和Al（III）。金属的活性根据它们对土壤和水中腐殖质化合物的亲和力进行分类。通过模型实验测试复合物的确定的条件稳定性常数，并且证明Fe和Al离子具有比碱土金属，Pb，Cu和Zn的离子更高的条件稳定性常数。此外，已经鉴定了铝离子和铁对铜和铅络合的影响以及铅和铜对钴和镍络合的影响。在大量湖泊中的金属形式基于实验结果计算。描述了欧洲俄罗斯和西西伯利亚湖泊水中的形式分布金属的主要化学机制。

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