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Fabrication of Transparent Conductive Thin Film Electrodes Based on Ag Nanowire on Transparent Substrates Using the Spray Method for Photovoltaic Applications

机译:基于透明导电薄膜电极的透明导电薄膜电极,采用光伏应用的透明基材上的透明基材

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摘要

Materials with a remarkable combination of high electrical conductivity as well as optical transparency are playing a key role for opto-electronic devices. In addition to these specific electro-optical properties, transparent conductive materials should, for many applications, be lightweight, flexible, low-cost, non toxic and compatible with mass production techniques. In these regards, the use of Ag nanowire (Ag NW) networks appears to be a promising approach. In this study, Ag NW electrodes were fabricated by a novel spray injection method. The number of pulses was varied resulting in different network morphologies. Coatings were systematically characterised structurally, electrically and optically via SEM, four-point probe measurements and spectrophotometry, respectively. Semi uniform layers of nanowires with large haze coefficients have been obtained over large areas. Thermal annealing was shown to increase the nanowire film conductance resulting in 16 Ω/sq surface resistance and up to 73% maximal total transmittance. Films showed average optical transparencies superior to that of ITO over the 250-2500 nm range. Finally, encapsulation of Ag NWs within a matrix of ZnO nanoparticles greatly enhanced the thermal stability of these networks.
机译:具有显着组合的高导电性和光学透明度的材料正在为光电设备发挥关键作用。除了这些特定的电光特性外,透明的导电材料还应用于许多应用,重量轻,柔韧,低成本,无毒,与大规模生产技术相容。在这些方面,AG纳米线(AG NW)网络的使用似乎是一种有希望的方法。在该研究中,通过新型喷射注射方法制造Ag NW电极。脉冲数量变化,导致不同的网络形态。通过SEM,四点探针测量和分光光度法,在结构上,通过SEM,四点探针测量和分光光度法进行系统地表征。在大面积上获得了具有大雾系数的半均匀纳米线层。显示热退火显示纳米线膜传导,导致16Ω/ Sq的表面电阻和最大总透射率高高达73%。电影显示平均光学透明胶片优于ITO,在250-2500nm范围内。最后,在ZnO纳米粒子的基质中封装Ag NWs大大提高了这些网​​络的热稳定性。

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