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energy Transfer of Photosynthesising Centres In Polymer Chain Excited By Infrared Radiation

机译:红外辐射激发的聚合物链中光合作用中心的能量转移

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In this paper, using infrared spectra and the theory of excitions, the matrix element of interaction Hamiltonian taken between the initial state and the final state of the polymer chain system has been established and exciton absorption spectra in polymer chains excited by infrared multiphoton are studied. The electron motion, in polymers excited by infrared multiphoton, is accompanied by local deformation of the chain. for energy transfer of photosynthesising centres for chlorophyll biopolymer, in constant frequency intensity of infrared radiation, our calculation is in agreement with experimental measurement of the absorption spectra. It would be important to study the dynamic process of biopolymer by infrared radiation.
机译:本文利用红外光谱和激发理论,建立了聚合物链体系初始状态和最终状态之间相互作用的哈密顿相互作用的矩阵元素,研究了红外多光子激发的聚合物链中的激子吸收光谱。在红外多光子激发的聚合物中,电子运动伴随着链的局部变形。对于叶绿素生物聚合物光合作用中心的能量转移,在恒定频率的红外辐射强度下,我们的计算与吸收光谱的实验测量相符。通过红外辐射研究生物聚合物的动态过程将很重要。

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