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Anode-supported SOFCs with Electrolyte Thin Films Prepared by Spray Coating

机译:喷涂法制备的带有电解质薄膜的阳极支撑SOFC

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Dense gadolinium doped ceria (GDC) electrolyte thin films were prepared on porous NiO-GDC substrates by spray coating process. Microstructure of the GDC thin films and effect of preparation process on the microstructure were examined. SEM results show that uniform and dense GDC thin films with a thickness of approximately 1 μm were successfully prepared on porous NiO-GDC anodes. Anode-supported single cell with the thin GDC electrolyte film was tested using humidified hydrogen as a fuel, and exhibited relatively high electrical performance at low operating temperature (the maximum power density of 135 mW/cm~2 at 600 ℃). This means that the thin GDC film may be applicable to an electrolyte for anode-supported SOFCs. The experimental results suggest that the spray coating method developed in this study may offer a useful route for preparing thin and dense electrolytes of SOFCs.
机译:通过喷涂法在多孔NiO-GDC基底上制备了高密度掺杂do的二氧化铈(GDC)电解质薄膜。研究了GDC薄膜的微观结构和制备工艺对其微观结构的影响。 SEM结果表明,在多孔NiO-GDC阳极上成功制备了厚度约1μm的均匀致密的GDC薄膜。使用加湿的氢气作为燃料测试了具有GDC电解质薄膜的阳极支撑单电池,并在较低的工作温度(600℃下的最大功率密度为135 mW / cm〜2)下表现出较高的电性能。这意味着薄的GDC膜可适用于阳极支撑的SOFC的电解质。实验结果表明,本研究开发的喷涂方法可能为制备薄而致密的SOFC电解质提供有用的途径。

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