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Development of Novel Functionally Graded Al_2O_3-Lanthanum Hexaaluminate Ceramics for Thermal Barrier Coatings

机译:用于热障涂层的新型功能梯度Al_2O_3-镧镧六铝酸盐陶瓷的开发

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摘要

Lanthanum hexaaluminate (LHA) has superior thermo-chemical stability at temperatures higher than 1000 ℃ and is a promising competitor to Y-ZrO_2-based thermal barrier coatings (TBCs). The yet unresolved problem is control of microstructure of high LHA content ceramics and adjustment of porosity upon, to arrive at a material exhibiting low thermal conductivity at high temperature combined with structural reliability. Therefore, a functionally graded alumina/lanthanum hexaaluminate (FGLHA) with a gradient in composition was developed. The thermal diffusivity and thermal conductivity of FGLHA were compared with the one of the monolithic composite ceramics. The alumina-rich composites showed excellent mechanical properties whereas the LHA-rich composites presented lower thermal conductivity.
机译:六铝酸镧(LHA)在高于1000℃的温度下具有出色的热化学稳定性,并且是基于Y-ZrO_2的热障涂层(TBC)的有希望的竞争对手。尚未解决的问题是控制高LHA含量的陶瓷的微观结构并调节孔隙率,从而获得一种在高温下显示出低导热率和结构可靠性的材料。因此,开发了具有梯度成分的功能梯度氧化铝/六铝酸镧(FGLHA)。将FGLHA的热扩散率和导热率与一种整体复合陶瓷进行了比较。富含氧化铝的复合材料显示出优异的机械性能,而富含LHA的复合材料显示出较低的热导率。

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