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Bioinspired self-assembly for organic electro-optics

机译:受生物启发的有机光电自组装

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摘要

Organic electro-optic materials have potential applications in optical communication and data processing. One major obstacle to the realization of the full potential of OEO materials is the interchromophore electrostatic interactions which have prevented the poling-induced chromophore order parameter from reaching above 0.3. In this presentation, we show designs of new chromophores that have ring structures surrounding the center of chromophores to prevent chromophores from packing in the antiparallel fashion, and modification of such chromophores with complementary DNA nucleobases to strengthen head-tail interactions.
机译:有机光电材料在光通信和数据处理中具有潜在的应用。实现OEO材料的全部潜力的主要障碍是发色团间静电相互作用,阻止了极化诱导的发色团有序参数达到0.3以上。在此演示文稿中,我们展示了新发色团的设计,这些发色团具有围绕发色团中心的环结构,以防止发色团以反平行方式堆积,并使用互补的DNA核碱基修饰此类发色团以增强头尾相互作用。

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