Effect of charge carrier blocking layers on poling nonlinear optic polymers

机译：电荷载流子阻挡层对极化非线性光学聚合物的影响

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In our previous work we demonstrated a 3X increase in the nonlinearity, or electro-optic (EO) coefficient of the nonlinear optic (NLO) polymer disperse red 1 :Polymethylmethacrylate (DR1: PMMA) by introducing a thin guanine nucleobase interfacial buffer layer, deposited between the NLO polymer and the cathode and a thin bathocuproine (BCP) interfacial buffer layer, deposited between the NLO polymer and the anode, being poled at 100 V/μm. In addition, we observed a 40% increase in EO coefficient by depositing either a thin sol-gel derived titanium dioxide layer or a thin guanine layer on either the anode or cathode side of the structure, poling at 100 V/μm. This paper addresses our analysis of these differences and is based on surface resistance.

机译：在我们之前的工作中，通过引入薄的鸟嘌呤核碱基界面缓冲层，沉积了非线性光学（NLO）聚合物分散红色1：聚甲基丙烯酸甲酯（DR1：PMMA）的非线性或电光（EO）系数，使之增加了3倍。在NLO聚合物和阴极之间形成一层薄的铜环（BCP）界面缓冲层，该界面缓冲层沉积在NLO聚合物和阳极之间，以100 V /μm极化。此外，我们观察到通过在结构的阳极或阴极侧沉积一层溶胶-凝胶衍生的二氧化钛薄层或鸟嘌呤薄层，以100 V /μm极化的方式将EO系数提高40％。本文介绍了我们对这些差异的分析，并基于表面电阻。

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来源
《Nanobiosystems: Processing, characterization, and applications IX》|2016年|992802.1-992802.6|共6页
会议地点 San Diego CA(US)
作者
Fahima Ouchen; Emily Heckman; Larry Dalton; Francois Kajzar; Ileana Rau; James Grote;
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作者单位

US Air Force Research Laboratory, Materials and Manufacturing Directorate, Wright-Patterson Air Force Base, OH 45433 ,University of Dayton Research Institute, Dayton, OH 45469;

US Air Force Research Laboratory, Sensors Directorate, Wright-Patterson Air Force Base, OH 45433;

Department of Chemistry, University of Washington, Seattle, WA 98195-1700;

Universitatea Politehnica din Bucuresti, Bucuresti, Romania;

Universitatea Politehnica din Bucuresti, Bucuresti, Romania;

US Air Force Research Laboratory, Materials and Manufacturing Directorate, Wright-Patterson Air Force Base, OH 45433;

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原文格式 PDF
正文语种 eng
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关键词
nonlinear optic polymer; opto-electronic; electro-optic modulator; electro-optic coefficient; guanine; nucleobase; bathocuproine; interfacial; buffer; surface resistance;

机译：非线性光学聚合物光电电光调制器电光系数鸟嘌呤核碱基碱性铜界面缓冲;表面电阻;

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1. Charge carrier generation and electron blocking at interlayers in polymer solar cells [J] . Chunhong Yin, Bjoern Pieper, Burkhard Stiller, Applied Physics Letters . 2007,第13期

机译：聚合物太阳能电池中间层的电荷载流子产生和电子阻挡
2. POLING DYNAMICS AND EFFECTS OF TRAPPED CHARGE IN POLED POLYMER FILMS FOR NONLINEAR OPTICAL APPLICATIONS [J] . Pauley MA., Jen AKY., Wang CH. Macromolecules . 1996,第22期

机译：非线性光学应用的POLED聚合物薄膜的极化动力学和电荷陷阱效应
3. POLING DYNAMICS AND INVESTIGATION INTO THE BEHAVIOR OF TRAPPED CHARGE IN POLED POLYMER FILMS FOR NONLINEAR OPTICAL APPLICATIONS [J] . Pauley MA., Wang CH., Guan HW. The Journal of Chemical Physics . 1996,第17期

机译：非线性光学应用的POLED聚合物薄膜的极化动力学及其诱捕行为的研究
4. Effect of charge carrier blocking layers on poling nonlinear optic polymers [C] . Fahima Ouchen, Emily Heckman, Larry Dalton, Conference on nanobiosystems: Processing, characterization, and applications IX . 2016

机译：电荷载体阻塞层对抛光非线性光学聚合物的影响
5. Novel phosphors, charge carriers and charge blockers for organic light emitting devices. [D] . Li, Jian. 2005

机译：用于有机发光器件的新型荧光粉，电荷载流子和电荷阻挡剂。
6. Anisotropic attosecond charge carrier dynamics and layer decoupling in quasi-2D layered SnS2 [O] . Calley N. Eads, Dmytro Bandak, Mahesh R. Neupane, -1

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7. Efficiency of solution-processed multilayer polymer light-emitting diodes using charge blocking layers [O] . Kasparek C., Rörich I., Blom P., 2018

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8. Poling Dynamics and Effects of Trapped Charge in Poled Polymer Films forNonlinear Optical Applications [R] . Pauley, M. A., Wang, C. H., Jen, A. K. 1996

机译：非线性光学应用中极化聚合物薄膜的极化电荷的极化动力学和效应

Effect of charge carrier blocking layers on poling nonlinear optic polymers

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