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Enhanced fluorescence and aggregation of rhodamine molecules dispersed in a thin polymer film in the presence of plasmonic nanostructures

机译:在等离子体纳米结构的存在下,分散在聚合物薄膜中的若丹明分子的荧光增强和聚集

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Optical properties of composite structures comprised of the island films of silver nanoparticles with a thin molecular layer of a dye rhodamine 6G were obtained and studied in this paper. In the near field of plasmonic nanoparticles enhancement and shifting of the maximums of the absorption and fluorescence spectra were observed. In the absorption and fluorescence spectra of thin molecular films with nanoparticles the new red-shifted band in comparison with spectra of thin films without nanoparticles was found. This band was associated with the formation of aggregates. Thus, the silver nanoparticles can contribute to fluorescence enhancement and formation of the aggregates in the rhodamine thin films.
机译:本文获得并研究了由银纳米粒子的岛膜和染料罗丹明6G分子薄层组成的复合结构的光学性能。在等离子体纳米粒子的近场中,观察到吸收和荧光光谱最大值的增强和移动。在具有纳米颗粒的薄膜的吸收和荧光光谱中,与没有纳米颗粒的薄膜的光谱相比,发现了新的红移带。该带与聚集体的形成有关。因此,银纳米颗粒可有助于荧光增强和若丹明薄膜中聚集体的形成。

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