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Physical and Photocatalytic Properties of TiO_2 Nanostructures Fabricated by Means of Glancing Angle Deposition

机译:掠角沉积制备的TiO_2纳米结构的物理和光催化性能

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摘要

Structural, optical and photocatalytic properties of various TiO_2 nanostructures prepared by glancing angle deposition (GLAD) and by electrochemical anodic oxidation of Ti were studied. The TiO_2 nanorods were prepared on unheated glass substrates by reactive sputtering of Ti in a mixture of Ar and O_2 gases in a glancing angle deposition (GLAD) regime. The crystal structure of the TiO_2 nanorods was characterized by X-ray diffraction (XRD) and the obtained spectra showed that both anatase and rutile phases are present in the GLAD deposited nanorods with the ratio which corresponds to the ratio of Ar and O_2 in the working gas. In addition, TiO_2 nanostructures were fabricated by electrochemical anodic oxidation of Ti films and Ti nanorods prepared by GLAD in the oxygen free atmosphere at 0.1 Pa of Ar.
机译:研究了通过掠角沉积(GLAD)和钛的电化学阳极氧化制备的各种TiO_2纳米结构的结构,光学和光催化性能。通过在掠射角沉积(GLAD)方式下在Ti和Ar_2和O_2气体的混合物中反应性溅射Ti,在未加热的玻璃基板上制备TiO_2纳米棒。通过X射线衍射(XRD)表征了TiO_2纳米棒的晶体结构,所得光谱表明,在GLAD沉积的纳米棒中既存在锐钛矿相又存在金红石相,其比例对应于工作中Ar和O_2的比例。加油站。此外,通过在0.1Pa Ar的无氧气氛中通过GLAD制备的Ti膜和Ti纳米棒的电化学阳极氧化,制备了TiO_2纳米结构。

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  • 来源
    《Nanotechnology-general》|2008年|49-58|共10页
  • 会议地点 Honolulu HI(US);Honolulu HI(US);Honolulu HI(US)
  • 作者单位

    National Institute for Materials Science, Micro-Nano Materials Engineering Group and Photocatalytic Materials Center, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan;

    National Institute for Materials Science, Micro-Nano Materials Engineering Group and Photocatalytic Materials Center, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan 'National Institute of Advanced Industrial Science and Technology, Research Center of Photovoltaics, AIST Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki, 305-8568, Japan;

    National Institute for Materials Science, Micro-Nano Materials Engineering Group and Photocatalytic Materials Center, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan;

    National Institute for Materials Science, Micro-Nano Materials Engineering Group and Photocatalytic Materials Center, 1-2-1 Sengen, Tsukuba;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 特种结构材料;
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