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MANGANESE DIOXIDES PROMISING CATHODE MATERIALS FOR LITHIUM BATTERIES

机译:用于锂电池的锰二氧化物有希望的阴极材料

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摘要

The production of 3C products in electronics information and communication has now been oriented toward wireless and portable electronic devices. Therefore the high performance components of the product are designed to be "lighter, thinner, short, smaller". For this reason urgent demand exist for secondary batteries that are more compact, lighter and higher energy density. The second big market of lithium batteries will be the electrical bikes and electrical cars. The battery industry requires the integration of various technologies in the field of chemistry, material science, know-how, etc. The continuous development on the theoretical side and furthermore a long period of experience in R&D groups are also needed. The market demands products to be lighter, reliable, with higher electric power capacity and improved safety design. The commercially available rechargeable lithium batteries refers to the Li-Ion battery which uses carbon powder as negative active electrode material and lithiated metallic oxides as cobaltate and nickelate for positive active electrode material. For the moment only LiCoO_2 (lithium cobaltate) as positive electrode material occupies the market. However, the cost of LiCoO_2 material is so high that it would take up too much of the battery cost and besides, its specific energy density is not the highest, therefore, it may be replaced by the concurrent LiNiO_2- The price of LiNiO_2 material is less expensive with the highest specific gravimetric capacity, but it is difficult for synthesis and treatment. Both materials are not environmentally friendly.
机译:电子信息和通信领域的3C产品生产现在已面向无线和便携式电子设备。因此,产品的高性能组件被设计为“更轻,更薄,更短,更小”。因此,迫切需要更紧凑,更轻和更高能量密度的二次电池。锂电池的第二大市场将是电动自行车和电动汽车。电池行业需要整合化学,材料科学,专有技术等领域的各种技术。理论上的不断发展以及在研发团队中的长期经验也是必需的。市场要求产品更轻,更可靠,具有更高的电功率容量和改进的安全设计。市售的可再充电锂电池是指锂电池,其使用碳粉作为负极活性电极材料,并使用锂化金属氧化物作为钴和镍酸盐作为正极活性电极材料。目前,仅作为正极材料的LiCoO_2(钴酸锂)占据了市场。然而,LiCoO_2材料的成本太高,以至于会占用过多的电池成本,此外,其比能量密度不是最高的,因此,它可以被并发的LiNiO_2代替-LiNiO_2材料的价格是具有最高的比重分析功能,但价格较低,但合成和处理困难。两种材料都不环保。

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