PHYSICAL CHEMISTRY OF LITHIUM INTERCALATION COMPOUNDS

机译：锂嵌入化合物的物理化学

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Lithium intercalation compounds are known to form complexes as electron donor systems. A charge transfer which can strongly affect the electronic properties of the host lattice, and a change of preferential crystallographic parameters without destruction of the original structure are the main effects occurring during intercalation. Optical spectroscopies such as Raman scattering, far-infrared reflectivity, absorption measurements, and photoluminescence have been carried out for the study of electronic and structural modification. In this paper, lattice dynamics and physico-chemical properties of various two-dimensional intercalated compounds, i.e. transition metal dichalcogenides, non-transition metal chalcogenides and layered oxides, are presented. Results are discussed with the aim of a better understanding of the intercalation process. Some guide lines are established for improving the performances of these materials in their most eminent applications.

机译：已知锂嵌入化合物会形成络合物作为电子给体系统。可以极大地影响主体晶格的电子性能的电荷转移以及在不破坏原始结构的情况下改变优先的晶体学参数是在插层过程中发生的主要作用。诸如拉曼散射，远红外反射率，吸收测量和光致发光的光学光谱学已经用于电子和结构修饰的研究。本文介绍了各种二维插层化合物的晶格动力学和理化性质，即过渡金属二硫属元素，非过渡金属硫属元素化物和层状氧化物。为了更好地理解插入过程，对结果进行了讨论。建立了一些指导方针，以改善这些材料在最突出的应用中的性能。

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《NATO Advanced Study Institute on New Trends in Intercalation Compounds for Energy Storage, Sep 22-Oct 2, 2001, Sozopol, Bulgaria》|2001年|p.209-233|共25页
会议地点 Sozopol(BG)
作者
C. JULIEN;
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Laboratoire des Milieux Desordonnes et Heterogenes, UMR 7603 Universite Pierre et Marie Curie 4 place Jussieu, case 86, 75252 PARIS cedex 05, France;

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正文语种 eng
中图分类能源与动力工程;
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PHYSICAL CHEMISTRY OF LITHIUM INTERCALATION COMPOUNDS

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