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Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) systems

机译:CaO-SiO2-M2O(M = K,Na)系统的热力学建模

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摘要

The aim of the present study is the CALPHAD modeling of the systems CaO-SiO2-M2O (M=K, Na) based on a careful review of the available literature data - phase diagram and thermodynamics - as well as own experiments. The heat capacities (Cp) of three compounds, CaSiO3, K2Ca2Si2O7 and K8CaSi10O25, (determined using drop calorimetry) were included in the optimization of the ternary phase diagram CaO-SiO2-K2O.
机译:本研究的目的是对CaO-SiO2-M2O(M = K,Na)体系进行CALPHAD建模,该过程基于对现有文献数据(相图和热力学)的仔细审查以及自己的实验。三元相图CaO-SiO2-K2O的优化中包括三种化合物CaSiO3,K2Ca2Si2O7和K8CaSi10O25的热容(Cp)(使用滴热法测定)。

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