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A Solid-State NMR Study of Boric Acid Doped in Poly(vinyl alcohol)

机译:聚乙烯醇中掺杂硼酸的固态NMR研究

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摘要

A multinuclear solid-state NMR study of boric acid doped in poly(vinyl alcohol) (PVA) is presented. The experiments used for PVA films include ~1H windowed Phase-Modulated Lee-Goldburg (wPMLG), and ~(11)B Magic-Angle Spinning (MAS), ~(11)B stationary NMR, ~(11)B Multiple-Quantum MAS, and ~1H-~(11)B CP and HETCOR at 14.1 and/or 21.6 T. The present analysis strongly suggests the possibility that the boric acid serves as a crosslinker with a coordination number other than four.
机译:提出了聚乙烯醇(PVA)中掺杂的硼酸的多核固态NMR研究。用于PVA薄膜的实验包括〜1H窗口相位调制的Lee-Goldburg(wPMLG)和〜(11)B魔角旋转(MAS),〜(11)B固定NMR,〜(11)B多重量子MAS和〜1H-〜(11)B CP和HETCOR在14.1和/或21.6 T时存在。本分析强烈暗示了硼酸可能用作配位数为4以外的交联剂的可能性。

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