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Preparation and characterization of ternary hierarchical carbon nanofibers surface- grafted with CNTs and coated with conductive polymer

机译:表面接枝碳纳米管并包覆导电聚合物的三元分层碳纳米纤维的制备与表征

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This study reports the fabrication and structural characterization of novel ternary hierarchical carbon nanofibers (CNFs) surface-grafted with carbon nanotubes (CNTs) and then coated with conductive polymer. During the process, CNFs were produced by carbonization of as-electrospun polyacrylonitrilenanofibers with the diameter of ~200-400 nm, followed by CNT-growth via chemical vapor deposition (CVD). Ultrathin PANI film was further deposited onto the porous CNT-grafted CNFs via in-situ polymerization of anilines in aqueous solution. Such nanostructures can be used as electrodes for use in supercapacitors, in which the PANI films supported by conductive CNT/CNF scaffolds can trigger favorable pseudocapacitive effect and meanwhile the carbon substrate keeps low electrical resistance during cycling. These unique hierarchal nanostructures are excellent candidates for use as electrodes in high-performance supercapacitors for energy storage and management.
机译:这项研究报告了表面接枝了碳纳米管(CNT)然后涂覆了导电聚合物的新型三元分层碳纳米纤维(CNF)的制备和结构表征。在此过程中,CNF是通过碳化直径约200-400 nm的电纺聚丙烯腈三碳纳米纤维,然后通过化学气相沉积(CVD)进行CNT生长来生产的。通过在水溶液中苯胺的原位聚合,将超薄PANI膜进一步沉积到多孔CNT接枝的CNF上。此类纳米结构可用作用作超级电容器的电极,其中由导电CNT / CNF支架支撑的PANI膜可触发良好的拟电容效应,同时碳基材在循环过程中保持低电阻。这些独特的层级纳米结构是用作用于能量存储和管理的高性能超级电容器中的电极的极佳候选者。

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