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Self-assembled materials and devices that process light

机译:自组装材料和处理光的设备

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Self-assembled superlattices (SASs) are intrinsically acentric and highly cross-linked structures. For organic electro-optics, they offer great advantages such as not requiring electric field poling for creating an acentric, EO-active microstructure and having excellent chemical, thermal, and orientational stabilities. In this paper, a greatly improved two-step all "wet-chemical" self-assembly (SA) approach is reported. Excellent radiation hardness of the SAS films is demonstrated by high-energy proton irradiation experiments. By introducing metal oxide nanolayers during SA, we show that the refractive indices of SAS films can be tuned over a wide range. Through special chromophore design, the optical absorption maxima of SAS films can also be greatly blue-shifted. Prototype waveguiding electro-optic modulators have been fabricated using the SAS films integrated with low-loss polymeric materials functioning as partial guiding and cladding layers. EO parameters such as the half-wave voltage and the effective electro-optic coefficient are reported.
机译:自组装超晶格(SAS)是本质上非中心且高度交联的结构。对于有机电光学,它们具有很大的优势,例如不需要电场极化即可产生偏心的EO活性微结构,并且具有出色的化学,热和取向稳定性。在本文中,报告了大大改进的两步全“湿化学”自组装(SA)方法。高能质子辐照实验证明了SAS膜具有出色的辐射硬度。通过在SA期间引入金属氧化物纳米层,我们表明SAS膜的折射率可以在很宽的范围内调节。通过特殊的生色团设计,SAS薄膜的最大光吸收也可以发生蓝移。原型波导电光调制器已使用集成有低损耗聚合物材料的SAS膜制成,该材料用作部分引导层和包层。报告了诸如半波电压和有效电光系数之类的EO参数。

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