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LARGE SCALE CO SEPARATION BY VPSA USING CUCL/ZEOLITE ADSORBENT

机译:使用CUCL /沸石吸附剂通过VPSA进行大规模CO分离

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摘要

Based on the principles that cuprous ions can form complex with carbon monoxide and salts can spontaneously disperse onto the surface of supports as a monolayer, a highly efficient CO adsorbent, CuCl/Zeoilte, has been made by heating a mixture of CuCl and a zeolite at a suitable temperature to disperse the CuCl onto the surface of the zeolite.This adsorbent has high CO adsorption capacity (>50ml/g at 1 atm. and ambient temperature) and high CO selectivity over H2, N2, CH4 and CO. Using this adsorbent in a VPSA process, a large scale plant has been designed and built in China for separation of CO from syngas. The feed gas contains about CO 30%, H2 41%, N2 17%,CO2 8%, CH4 2%, O2 0.4%,and saturated water. The plant can produce carbon monoxide 1700m3 per hour with purity >99% and recover >85%.
机译:基于亚铜离子可以与一氧化碳形成络合物且盐可以单层自发分散在载体表面的原理,通过在室温下加热CuCl和沸石的混合物制得了一种高效的CO吸附剂CuCl / Zeoilte。该吸附剂具有很高的CO吸附能力(在1个大气压和环境温度下> 50ml / g),并且在H2,N2,CH4和CO上具有很高的CO选择性。在VPSA工艺中,中国已设计建造了一座大型工厂,用于从合成气中分离出CO。原料气包含大约30%的CO,41%的H2、17%的N2、8%的CO2、2%的CH4、0.4%的O2和饱和水。该工厂每小时可生产一氧化碳1700m3,纯度> 99%,回收率> 85%。

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