• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文会议>Pacific Basin Conference on Adsorption Science and Technology; 20070522-26; Tianjing(CN) >NON-EQUILIBRIUM DYNAMIC ADSORPTION AND DESORPTION ISOTHERMS OF CO2 ON A K-PROMOTED HTLC
【24h】

NON-EQUILIBRIUM DYNAMIC ADSORPTION AND DESORPTION ISOTHERMS OF CO2 ON A K-PROMOTED HTLC

机译：K促进HTLC上CO2的非平衡动态吸附和脱附等温线

获取原文
获取原文并翻译 | 示例
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

A K-promoted HTlc was synthesized and tested for its reversible CO2 capacity between 250 and 500 ℃. Non-equilibrium dynamic adsorption and desorption isotherms were measured between 65 and 980 torr using 20 or 50 torr steps and a 45 min duration between steps. The absolute CO2 capacity on K-promoted HTlc increased with decreasing temperature, with CO2 loadings of 2.25 and 1.02 mol/kg respectively at 250 and 500 ℃ and 980 torr. The reversible CO2 working capacity obtained between 65 and 980 torr exhibited a maximum at 450 ℃, with a value of 0.55 mol/kg compared to 0.11 and 0.46 mol/kg at 250 and 500 ℃, respectively. It was surmised that three temperature dependent, highly coupled, completely reversible, equilibrium driven but kinetically limited reactions were taking place, with the first one being a rapid and reversible chemisorption of CO2 that initiated the entire process.
机译：合成了钾促进的HTlc，并测试了其在250至500℃之间的可逆CO2容量。使用20或50托的步长和45分钟的间隔时间，在65至980托之间测量了非平衡动态吸附和解吸等温线。 K促进HTlc的绝对CO2容量随着温度的降低而升高，在250和500℃和980 torr下的CO2负荷分别为2.25和1.02 mol / kg。在65到980托之间获得的可逆CO2工作能力在450℃时表现出最大值，其值为0.55 mol / kg，而在250和500℃时分别为0.11和0.46 mol / kg。据推测，发生了三个与温度有关的，高度耦合的，完全可逆的，平衡驱动但动力学受限制的反应，其中第一个反应是快速且可逆的CO2化学吸附，从而引发了整个过程。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号