首页> 外文会议>Pacific Rim International Conference on Advanced Materials and Processing(PRICM 5) pt.1; 20041102-05; Beijing(CN) >Preparation of Nanocrystalline NiAl Compounds and Composites by Mechanical Alloying
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Preparation of Nanocrystalline NiAl Compounds and Composites by Mechanical Alloying

机译:机械合金化制备纳米晶NiAl化合物及复合材料

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During the past ten years, mechanical alloying/ball milling has been employed to successfully synthesize nanocrystalline NiAl intermetallic compounds (NiAl, NiAl (Cr,Co,Ti,Fe)) and composites (NiAl-TiC, NiAl-TiB_2, NiAl-HfC, NiAl-HfB_2) in our group, namely, by means of self-sustained reaction. During the mechanical alloying process, an abrupt temperature rise has been observed. The large heat release from the formation of NiAl, as well as HfC, HfB_2, TiC, TiB_2 compounds is suggested to be the driven force of the self-sustained reaction. It is interested to observe that nanocrystalline NiAl exhibits very well microstructure stability during high temperature annealing. The alloying additions can decrease reaction rate and prolong the reaction time. With the increase of alloying additions, supersaturated solid solution even amorphization of NiAl has been formed. The nanocrystalline NiAl compounds show a rise of the compressive strength and the ductility at room temperature compared with that of the cast coarse crystalline compound.
机译:在过去的十年中,机械合金化/球磨已成功用于合成纳米晶NiAl金属间化合物(NiAl,NiAl(Cr,Co,Ti,Fe))和复合材料(NiAl-TiC,NiAl-TiB_2,NiAl-HfC, NiAl-HfB_2),即通过自持反应。在机械合金化过程中,已经观察到温度急剧上升。 NiAl的形成以及HfC,HfB_2,TiC,TiB_2化合物释放的大量热量被认为是自持反应的驱动力。令人感兴趣的是,观察到纳米晶NiAl在高温退火过程中表现出非常好的微观结构稳定性。合金添加会降低反应速率并延长反应时间。随着合金添加量的增加,已形成过饱和固溶体甚至NiAl非晶化。与铸造的粗晶化合物相比,纳米晶NiAl化合物在室温下显示出抗压强度和延展性的提高。

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