Influence of Introducing a Benzyl Group on Physical and Electrochemical Properties of Bis(fluorosulfonyl)amidc-Based Phosphonium Ionic Liquids

机译：引入苄基对双（氟磺酰基）酰胺基Ph离子液体的物理和电化学性能的影响

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The physical and electrochemical properties of room-temperature ionic liquids based on quaternary phosphonium cations containing a benzyl group in combination with bis(fluorosulfonyl)amide anion. It was found that the benzylphosphonium RTILs showed lower melting points, lower viscosities and higher conductivities than those of the corresponding TFSA-based benzylphosphonium and ammonium RTILs. The thermal stability of the benzylphosphonium RTILs was significantly improved by introducing a phenyl group into the phosphonium cations. The introduction of a phenyl group tended to reduce the electrochemical stability of the benzylphosphonium RTILs.

机译：基于含有苄基和双（氟磺酰基）酰胺阴离子的季phospho阳离子的室温离子液体的物理和电化学性质。发现苄基phosphRTIL显示出比相应的基于TFSA的苄基phosph和铵RTIL更低的熔点，更低的粘度和更高的电导率。通过将苯基引入phospho阳离子中，可以大大改善苄基RT RTIL的热稳定性。苯基的引入倾向于降低苄基RTRTIL的电化学稳定性。

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《Physical and Analytical Electrochemistry (General) - 224th ECS Meeting》|2013年|91-97|共7页
会议地点 San Francisco CA(US)
作者
K. Tsunashima; C. Nagai; M. Matsumiya;
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Department of Materials Science, Wakayama National College of Technology, 77 Noshima, Nada-cho, Gobo, Wakayama 644-0023, Japan;

Department of Materials Science, Wakayama National College of Technology, 77 Noshima, Nada-cho, Gobo, Wakayama 644-0023, Japan;

Graduate School of Environment and Information Sciences, Yokohama National University, 79-2 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan;

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4. Influence of Introducing a Benzyl Group on Physical and Electrochemical Properties of Bis(fluorosulfonyl)amidc-Based Phosphonium Ionic Liquids [C] . K. Tsunashima, C. Nagai, M. Matsumiya Symposium on Physical and Analytical Electrochemistry Division General Session . 2014

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Influence of Introducing a Benzyl Group on Physical and Electrochemical Properties of Bis(fluorosulfonyl)amidc-Based Phosphonium Ionic Liquids

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