Direct Electropolymerization of Copolymer Electrolyte into 3D Nano-architectured Electrodes for High-Performance Hybrid Li-ion Microbatteries

机译：将共聚物电解质直接电聚合成3D纳米结构电极，用于高性能混合锂离子微电池

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It is shown that electropolymerization can be addopled to deposit a a copolymer electrolyte (PEO-b-PMMA) into titania nanotubes for the fabrication of on-chip microbatteries. The copolymer embedded TiO_2 nanotubes show good electrochemical performance, which is due to the improved electrode/electrolyte interface achieved by filling the nanotubes with the copolymer. The titania nanotubes and the copolymer-embedded nanotubes are characterized by surface analysis techniques including (SEM, EDX. FTTR). This electrolyte deposition process can be extended to any kind of 3D nano-architectured electrodes. The electrochemical performance was evaluated in lithium test cells.

机译：结果表明，可以进行电聚合以将共聚物电解质（PEO-b-PMMA）沉积到二氧化钛纳米管中，以制造片上微电池。嵌入共聚物的TiO_2纳米管显示出良好的电化学性能，这是由于通过用共聚物填充纳米管而获得的改善的电极/电解质界面。二氧化钛纳米管和嵌入共聚物的纳米管通过包括（SEM，EDX.FTTR）在内的表面分析技术来表征。该电解质沉积过程可以扩展到任何种类的3D纳米结构电极。在锂测试电池中评估了电化学性能。

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来源
《Pits and pores 4: New materials and applications - in memory of ulrich gosele》|2010年|p.77-85|共9页
会议地点 Las Vegas NV(US);Las Vegas NV(US)
作者
Nana Amponsah Kyeremateng; Frederic Dumur; Philippe Knauth; Thierry Djenizian;
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作者单位

University of Aix-Marseille I, II, III - CNRS, Laboratoire Chimie Provence (UMR 6264), Electrochemistry of Materials Research Group, Centre Saint-Jerome, F-13397 Marseille Cedex 20, France;

University of Aix-Marseille I, II, TTT - CNRS, Laboratoire Chimie Provence (UMR 6264) Equipe : CROPS, Centre Saint-Jerome, F-13397 Marseille Cedex 20, France;

University of Aix-Marseille I, II, III - CNRS, Laboratoire Chimie Provence (UMR 6264), Electrochemistry of Materials Research Group, Centre Saint-Jerome, F-13397 Marseille Cedex 20, France;

University of Aix-Marseille I, II, III - CNRS, Laboratoire Chimie Provence (UMR 6264), Electrochemistry of Materials Research Group, Centre Saint-Jerome, F-13397 Marseille Cedex 20, France;

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专利

1. Electropolymerization of copolymer electrolyte into titania nanotube electrodes for high-performance 3D microbatteries [J] . Kyeremateng N.A., Dumur F., Knauth P., Electrochemistry communications . 2011,第8期

机译：将共聚物电解质电聚合成用于高性能3D微型电池的二氧化钛纳米管电极
2. Electrodeposited copolymer electrolyte into nanostructured titania electrodes for 3D Li-ion microbatteries [J] . Nana Amponsah Kyeremateng, Frederic Dumur, Philippe Knauth Comptes Rendus Chimie . 2013,第1期

机译：将共聚物电解质电沉积到用于3D锂离子微电池的纳米结构二氧化钛电极中
3. High-power lithium-ion microbatteries from imprinted 3D electrodes of sub-10 nm LiMn2O4/Li4Ti5O12 nanocrystals and a copolymer gel electrolyte [J] . Li Wenhao, Christiansen Troels Lindahl, Li Cheng, Nano Energy . 2018,第期

机译：来自Sub-10nm LiMn2O4 / Li4Ti5O12纳米晶体和共聚物凝胶电解质的压印3D电极的高功率锂离子微滴膜
4. Direct Electropolymerization of Copolymer Electrolyte into 3D Nano-architectured Electrodes for High-Performance Hybrid Li-ion Microbatteries [C] . Nana Amponsah Kyeremateng, Frederic Dumur, Philippe Knauth, ECS Meeting . 2011

机译：用于高性能杂交锂离子微滴乳的三维纳米架构电极的共聚物电解质的直接电聚合
5. Virus enabled 3d nano-array electrodes for integrated Lithium/Sodium-ion microbatteries. [D] . Liu, Yihang. 2013

机译：具有病毒功能的3d纳米阵列电极，用于集成锂/钠离子微电池。
6. Highly conformal electrodeposition of copolymer electrolytes into titania nanotubes for 3D Li-ion batteries [O] . Nareerat Plylahan, Nana Amponsah Kyeremateng, Marielle Eyraud, 2012

机译：将共聚物电解质高度共形地电沉积到3D锂离子电池的二氧化钛纳米管中
7. Hierarchical self-assembled structures based on nitrogen-doped carbon nanotubes as advanced negative electrodes for Li-ion batteries and 3D microbatteries [O] . Sharifi, Tiva, Valvo, Mario, Gracia-Espino, Eduardo, 2015

机译：基于氮掺杂碳纳米管的分层自组装结构，作为锂离子电池和3D微型电池的高级负极

Direct Electropolymerization of Copolymer Electrolyte into 3D Nano-architectured Electrodes for High-Performance Hybrid Li-ion Microbatteries

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