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Photoexcited Silicon Nanocrystals as Multifunctional Spin-Flip Activator

机译:光激发硅纳米晶体作为多功能自旋翻转活化剂

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摘要

Nano-sized silicon crystals have entirely new physical properties which do not occur in its bulk form. Investigation of its photoluminescence properties can explain the mechanism of transferring energy from photoexcited excitons confined in silicon nanocrystals to energy accepting substances via electron exchange mechanism. This excitation process changes the electronic spin structure of the acceptor molecule, which is forbidden in the dipole approximation, and therefore it requires the involvement of photosensitizers.
机译:纳米级硅晶体具有全新的物理特性,不会以其整体形式出现。对它的光致发光性质的研究可以解释通过电子交换机制将能量从硅纳米晶体中限制的光激发激子转移到能量接受物质的机制。该激发过程改变了受体分子的电子自旋结构,这在偶极近似中是被禁止的,因此需要光敏剂的参与。

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